Rivers and ponds near the Erdenet mine, one of the world’s largest copper-molybdenum mines, exhibit high concentrations of molybdenum (Mo). This study evaluates the distribution and chemical speciation of Mo in surface sediments from ponds and rivers in Erdenet city to elucidate the mobility and solubility of Mo in the surface aquatic environments in the area. The waters and sediments were collected in two shallow ponds connected to the tailing pond and from three rivers flowing through Erdenet city. The distribution and chemical speciation of Mo in the sediments were examined using five-step sequential extraction and X-ray absorption fine structure (XAFS) analyses. The XAFS spectra of the sediments showed that large amounts of Mo in the sediments are molybdate or polymeric molybdate, weakly adsorbed onto ferrihydrite. Sequential extraction consistently showed a large amount of Mo distributed in the labile fractions. Results suggest that the surface sediments from ponds and rivers play a role as secondary contamination sources of Mo rather than as sinks of Mo in the area.

The nature of mineral precipitations in terrestrial alkaline soda lakes provides insights into the water chemistry of subsurface oceans on icy bodies in the outer solar system. Saturation analyses of terrestrial alkaline lakes have shown that the solution chemistries of lake waters are generally controlled by the presence of monohydrocalcite (MHC) and amorphous Mg-carbonate (AMC). However, direct observations of the formation of these metastable carbonates in natural alkaline lakes have been limited. This study provides evidence of in situ MHC formation in alkaline lakes, based on the water chemistry and mineralogy of suspended matter in Olgoy, Boon Tsagaan, and Orog Lakes (Valley of Gobi Lakes, Mongolia). The solution chemistries were close to saturation with respect to MHC and AMC, consistent with other alkaline lakes worldwide. Suspended matter was separated by the ultracentrifugation of lake water following freeze-drying. Our results show that MHC is the common mineral phase in the suspended matter. These observations confirm that MHC is the direct authigenic product of evaporation in alkaline lakes. The carbonate fraction in suspended matter from Olgoy Lake has a Mg/Ca ratio of 0.4, suggesting the formation of AMC in association with MHC. Based on the dissolution equilibria of AMC and MHC, we predict the Mg²⁺, Ca²⁺, and total dissolved carbonate concentrations in Enceladus’ ocean to be ~1 mmol/kg, ~10 μmol/kg, and 0.06–0.2 mol/kg, respectively, in the presence of AMC and MHC. We propose that the measurements of Mg contents in plumes will be key to constraining the total dissolved carbonate concentrations and chemical affinities of subsurface oceans on Enceladus and other alkaline-carbonate ocean worlds.

To understand how the climate system works in the continental interior, sediment cores that are approximately 30-cm long were taken from Olgoy, Boontsagaan, and Orog lakes, Mongolia. These cores were analyzed and compared with meteorological data (air temperature, precipitation, and wind) from climate stations in the study area. Comparison of metrological data from four stations shows similar climate fluctuations. When the temperature was high, less precipitation occurred in general. The sedimentary features measured in this study were water content, organic matter, carbonate, amorphous silica contents, whole and mineral grain size, and grain density. Excess ²¹⁰Pb measurements were used to estimate sedimentary ages. According to principal component analysis (PCA), temperature correlates well to sediment characteristics in Olgoy Lake. Whole and mineral grain sizes are coarser when the temperature is high, while the amorphous-silica concentration is lower. A coarse grain size is interpreted to reflect low lake levels due to evaporation under high temperature with less precipitation. Amorphous silica may be from surrounding plants and reflects less vegetation when the temperature is high. However, in the recent 30 years, after the social system changed and overgrazing became a problem, the amount of amorphous silica has positively correlated with temperature on a short time scale. In the past 30 years, with less vegetation, amorphous silica has mainly come from weathered mineral particles. High temperature caused a thick, weathered mantle for each mineral particle, resulting in high amorphous-silica concentration. In Boontsagaan Lake, whole and mineral grain sizes are coarser when the wind speed is increased. Low precipitation correlates with a decrease in organic matter and an increase in carbonate and amorphous silica. In Orog Lake, it is difficult to establish an age model due to dried-up events. Some fluctuations in sedimentary characteristics may correspond to extreme events, such as earthquakes, and natural hazards, such as dzuds (harsh winters).

The Erdenet mine (Erdenet, Mongolia) is a copper–molybdenum open pit mine with a huge tailing pond and is located next to a residential area. As the sources of drinking water in this area rely on groundwater and can be categorized into public or private wells, we aimed to assess the groundwater quality of the different types of drinking water wells. To accomplish our goal, we analyzed 18 trace metals (As, Ba, Bi, Cd, Co, Cr, Cs, Cu, Ga, Mo, Ni, Pb, Se, Sr, Th, U, V, Zn) and 8 major metals (Al, Ca, Fe, K, Mg, Mn, Na, Si) samples using ICP-MS and ICP-OES, and the heavy metal pollution index, heavy metal evaluation index, and degree of contamination were calculated. The most concerning point is that the Mo concentration of waste water in the Erdenet mine tailing pond and at a natural spring located 300 m from the tailing pond was 1100 μg/L, which greatly exceeds the WHO permissible concentration for Mo of 70 μg/L. Furthermore, high Ca and Mg concentrations at all private wells indicated that consumers of these wells are more vulnerable to any type of water pollution, as these wells are not built with any disinfection or treatment system. A modified categorization of the water quality indices showed that the public and private wells have low–medium contamination and that the tailing pond seepage water, along with its nearest spring, have a high degree of contamination. Because many private wells are located along the tailing pond and used directly without any treatment, we suggest a continuous evaluation and monitoring of the groundwater quality in this area.