In this paper, a green synthesis method for ZSM-5 zeolite is explored to reduce the synthesis cost, environmental hazard, and reaction temperatures. For the ZSM-5 samples prepared at low temperatures, the influence of factors such as the hydrothermal temperature, crystallization time, and the number of seeds is systematically investigated. The adsorption isotherm of CO₂ is used for fitting analysis of adsorption models and determination of the adsorption selectivity. The results show that the best one among the three samples presents the highest CO₂ adsorption capacity of 2.39 mmol/g at 273 K and 15 bar. It is prepared with a hydrothermal temperature of 393 K, crystallization time of 7 days, and a seed crystal of 1 wt %. The dual-site Langmuir model can well describe the experimental data, indicating that double adsorption sites rather than the simple single-layer adsorption are dominant in samples. As the pressure increases, the adsorption capacity calculated by the model is much lower than the actual value with a deviation index of 12.5%. At a pressure of 1 bar, the optimal selectivity is attained with sample L-20, viz., CO₂/N₂ of 34.3 and CO₂/O₂ of 70.2. The green synthesis method reported in this research can be used to successfully prepare ZSM-5 zeolite, and it shows excellent CO₂ adsorption performance. In addition, the use of low-cost raw materials and template-free synthesis methods will facilitate the large-scale application of green synthesis processes in the future.

Framework hybrid W-ZSM-5 and W-silicalite-1 zeolites were synthesized by hydrothermal methods using rice husk ash (RHA) as a silicon raw material. RHA is a low-cost precursor material, and its use can also alleviate the environmental and human health related problems that may occur when it is stacked in open fields. A series of comparative samples were characterized by XRD, FTIR, ICP-OES, SEM, N₂ adsorption–desorption and pore size analysis in order to examine their crystal structure, hybrid state, morphology and textural properties. The maximum CO₂ adsorption capacities of W-ZSM-5 and W-silicalite-1 are 81.69 and 69.96 cm³ g⁻¹, respectively, measured at 15 bar. The isotherms of CO₂, N₂ and O₂ are perfectly fitted by the Toth model, and it is noted that the presence of Al atoms increases the heterogeneity. It can be seen that the greater the heterogeneity of the adsorbent, the larger the CO₂ adsorption capacity achieved. The incorporation of tungsten into the framework does not affect the crystallization of the zeolite, but it prevents the formation of silanol and O–H groups at the adsorption sites. Therefore, the CO₂/H₂O selectivity of W-ZSM-5 is slightly higher than that of ZSM-5, and that of W-silicalite-1 is three times that of silicalite-1. W-ZSM-5/silicalite-1 are promising adsorbents for separating CO₂ under humid industrial conditions.

With the development of social economy, using lithium-ion batteries in energy storage in industries such as large-scale electrochemical energy storage systems will cause lithium resources to no longer meet demand. As such, sodium ion batteries have become one of the effective alternatives to LIBs. Many attempts have been carried out by researchers to achieve this, among which F-doping is widely used to enhance the electrochemical performance of SIBs. In this paper, we reviewed several types of transition metal oxide cathode materials, and found their electrochemical properties were significantly improved by F-doping. Moreover, the modification mechanism of F-doping has also been summed up. Therefore, the application and commercialization of SIBs in the future is summarized in the ending of the review.

Greenhouse gas emissions are significant contributors to global warming, and steel enterprises need to find more efficient and environmentally friendly solutions to reduce CO₂ emissions while maintaining high process efficiency and low production costs. Carbon capture and utilization (CCU) is a promising approach which can convert captured CO₂ into valuable chemicals, reducing dependence on fossil fuels and mitigating climate change. This study uses life cycle assessment (LCA) to compare the environmental impacts of BF-BOF steel plants with and without CCU. When evaluating seven scenarios, including three carbon capture and two carbon utilization technologies, against a baseline, the results demonstrate significant environmental benefits from implementing CCU technologies. Although the activated carbon TSA route for CO₂-based methanol production showed good environmental performance, its toxicity risks highlight the advantages of combining TSA with steel slag carbonation as a better non-toxic solution.