Despite a number of studies on biomass burning (BB) emissions in the atmosphere, observation of the associated aerosols and pollutants requires continuous efforts. Brazil, and more broadly Latin America, is one of the most important seasonal sources of BB, particularly in the Amazon region. Uncertainty about aerosol loading in the source regions is a limiting factor in terms of understanding the role of aerosols in climate modelling. In the present work, we investigated the Amazon BB episode that occurred during August 2019 and made the international headlines, especially when the smoke plumes plunged distant cities such as São Paulo into darkness. Here, we used satellite and ground-based observations at different locations to investigate the long-range transport of aerosol plumes generated by the Amazon fires during the study period. The monitoring of BB activity was carried out using fire related pixel count from the moderate resolution imaging spectroradiometer (MODIS) onboard the Aqua and Terra platforms, while the distribution of carbon monoxide (CO) concentrations and total columns were obtained from the infrared atmospheric sounding interferometer (IASI) onboard the METOP-A and METOP-B satellites. In addition, AERONET sun-photometers as well as the MODIS instrument made aerosol optical depth (AOD) measurements over the study region. Our datasets are consistent with each other and highlight AOD and CO variations and long-range transport of the fire plume from the source regions in the Amazon basin. We used the Lagrangian transport model FLEXPART (FLEXible PARTicle) to simulate backward dispersion, which showed good agreement with satellite and ground measurements observed over the study area. The increase in Rossby wave activity during the 2019 austral winter the Southern Hemisphere may have contributed to increasing the efficiency of large-scale transport of aerosol plumes generated by the Amazon fires during the study period.

Ozone plays an important role in the Earth’s atmosphere. It is mainly formed in the tropical stratosphere and is transported by the Brewer–Dobson Circulation to higher latitudes. In the stratosphere, ozone can filter the incoming solar ultraviolet radiation, thus protecting life at the surface. Although tropospheric ozone accounts for only ~10%, it is a powerful GHG and pollutant, harmful to the health of the environment and living beings. Several studies have highlighted biomass burning as a major contributor to the tropospheric ozone budget. Our study focuses on the Natal site (5.40°S, 35.40°W, Brazil), one of the oldest ozone-observing stations in Brazil, which is expected to be influenced by fire plumes in Africa and Brazil. Many studies that examined ozone trends used the total atmospheric columns of ozone, but it is important to assess ozone separately in the troposphere and the stratosphere. In this study, we have used radiosonde ozone profiles and daily TCO measurements to evaluate the variability and changes of both tropospheric and stratospheric ozone separately. The dataset in this study comprises daily total columns of colocalized ozone and weekly ozone profiles collected between 1998 and 2019. The tropospheric columns were estimated by integrating ozone profiles measured by ozone sondes up to the tropopause height. The amount of ozone in the stratosphere was then deduced by subtracting the tropospheric ozone amount from the total amount of ozone measured by the Dobson spectrometer. It was assumed that the amount of ozone in the mesosphere is negligible. This produced three distinct time series of ozone: tropospheric and stratospheric columns as well as total columns. The present study aims to apply a new decomposition method named Empirical Adaptive Wavelet Decomposition (EAWD) that is used to identify the different modes of variability present in the analyzed signal. This is achieved by summing up the most significant Intrinsic Mode Functions (IMF). The Fourier spectrum of the original signal is broken down into spectral bands that frame each IMF obtained by the Empirical Modal Decomposition (EMD). Then, the Empirical Wavelet Transform (EWT) is applied to each interval. Unlike other methods like EMD and multi-linear regression (MLR), the EAWD technique has an advantage in providing better frequency resolution and thus overcoming the phenomenon of mode-mixing, as well as detecting possible breakpoints in the trend mode. The obtained ozone datasets were analyzed using three methods: MLR, EMD, and EAWD. The EAWD algorithm exhibited the advantage of retrieving ~90% to 95% of ozone variability and detecting possible breakpoints in its trend component. Overall, the MRL and EAWD methods showed almost similar trends, a decrease in the stratosphere ozone (−1.3 ± 0.8%) and an increase in the tropospheric ozone (+4.9 ± 1.3%). This study shows the relevance of combining data to separately analyze tropospheric and stratospheric ozone variability and trends. It highlights the advantage of the EAWD algorithm in detecting modes of variability in a geophysical signal without prior knowledge of the underlying forcings.

We used WRF-Chem to simulate ash transport from eruptions of Chile’s Calbuco volcano on 22–23 April 2015. Massive ash and SO₂ ejections reached the upper troposphere, and particulates transported over South America were observed over Argentina, Uruguay, and Brazil via satellite and surface data. Numerical simulations with the coupled Weather Research and Forecasting–Chemistry (WRF-Chem) model from 22 to 27 April covered eruptions and particle propagation. Chemical and aerosol parameters utilized the GOCART (Goddard Chemistry Aerosol Radiation and Transport) model, while the meteorological conditions came from NCEP-FNL reanalysis. In WRF-Chem, we implemented a more efficient methodology to determine the Eruption Source Parameters (ESP). This permitted each simulation to consider a sequence of eruptions and a time varying ESP, such as the eruption height and mass and the SO₂ eruption rate. We used two simulations (GCTS1 and GCTS2) differing in the ash mass fraction in the finest bins (0–15.6 µm) by 2.4% and 16.5%, respectively, to assess model efficiency in representing plume intensity and propagation. Analysis of the active synoptic components revealed their impact on particle transport and the Andes’ role as a natural barrier. We evaluated and compared the simulated Aerosol Optical Depth (AOD) with VIIRS Deep Blue Level 3 data and SO₂ data from Ozone Mapper and Profiler Suite (OMPS) Limb Profiler (LP), both of which are sensors onboard the Suomi National Polar Partnership (NPP) spacecraft. The model successfully reproduced ash and SO₂ transport, effectively representing influencing synoptic systems. Both simulations showed similar propagation patterns, with GCTS1 yielding better results when compared with AOD retrievals. These results indicate the necessity of specifying lower mass fraction in the finest bins. Comparison with VIIRS Brightness Temperature Difference data confirmed the model’s efficiency in representing particle transport. Overestimation of SO₂ may stem from emission inputs. This study demonstrates the feasibility of our implementation of the WRF-Chem model to reproduce ash and SO₂ patterns after a multi-eruption event. This enables further studies into aerosol–radiation and aerosol–cloud interactions and atmospheric behavior following volcanic eruptions.

O trabalho proposto tem como intuito avaliar as condições sinóticas durante o evento de queimadas na região amazônica no mês de agosto de 2019 o qual acabou acarretando no transporte de particulados para a região sudeste, impactando diretamente na cidade de São Paulo no dia 19 transformando o dia em noite. Para a avaliação, foi utilizado os dados de reanálise do ERA5 juntamente aos dados modelo HYSPLIT com objetivo de analisar a trajetória das parcelas de ar durante o evento. A partir das avaliações observou-se a passagem de um sistema frontal o qual teve como função a convergência de umidade e escoamento de ventos sobre a região de São Paulo favorecendo o desenvolvimento de nebulosidade. Além disso, o aumento de particulados ao longo da atmosfera pode ter contribuido como núcleo de condensação, podendo assim favorecer o aumento considerável de nuvens escuras durante o perı́odo da tarde no municı́pio impactando diretamente na radiação refletida dando um aspecto noturno para a cidade.