Silver-coated molybdenum is an optimum material selection to replace pure silver as solar cell interconnector. However, the low adhesive strength between Ag films and Mo substrate hinders the application of the interconnector, because it is difficult to form metallurgical bonding or compound in the film/substrate interface using conventional deposition. In order to improve the adhesion, some Ag particles were implanted into the surface of Mo substrate by ion beam-assisted deposition (IBAD) before the Ag films were deposited by magnetron sputtering deposition (MD). The objective of this work was to investigate the effect of different assisted ion beam energy on the film/substrate adhesive properties. In addition, the fundamental adhesion mechanism was illustrated. The results revealed that the adhesion between Ag films and Mo substrate could be greatly enhanced by IBAD. With the increase of the assisting ion beam energy, the adhesive strength first increased and then decreased, with the optimum adhesion being able to rise to 25.29 MPa when the energy of the assisting ion beam was 30 keV. It could be inferred that the combination of “intermixing layer” and “implanted layer” formed by the high-energy ion bombardment was the key to enhancing the adhesion between Ag films and Mo substrate effectively.
A series of novel nanoparticles-assembled Cu2O/Bi2O3 composites were synthesized by simple wet chemical reduction method. The synthesized materials were characterized by XRD, SEM, BET and FTIR. The microstructures are considered to be the nanoparticles-assembled mesoporous structure with large specific surface. The composited Bi2O3 refine the grain of Cu2O and increase the surface area of composites. When the molar ratio of composite is 5:1, the sample shows excellent adsorption capacity of removing methyl orange and the maximum adsorption capacity is 1533.2 mg/g. The performance of adsorption is attributed to the synergistic effects of high specific surface area and electrostatic interaction. In this work, the adsorption kinetic was investigated, which follows the pseudo-second-order kinetic model for the adsorption of methyl orange. The Cu2O/Bi2O3 composites can be reused through further visible light irradiation. The results indicate that the adsorption-photocatalysis have great potential in water treatment applications.
Ag, Mo, and Ag–Mo were respectively implanted into GH4169 alloy substrates without heating via ion-beam-assisted bombardment technology (IBAB). In addition, the wear performance under low sliding speed and applied load were researched at room temperature (RT). A small amount silver molybdate phase could be detected on the surface of the co-implanted GH4169 alloy bombarded by a high-energy ion beam. The average friction coefficients under the steady wear state had almost no change at all. Compared with the un-implanted GH4169 alloys, the wear rate of the GH4169 alloys with co-implantation of Ag and Mo was reduced by 75%. A large amount of the silver molybdate phase could be generated due to the tribo-reaction on the worn surface during sliding. It benefits the formation of continuous oxide layers as lubrication and protected layers, leading to the change in the predominant wear mechanism from abrasion and adhesion wear to oxidation wear.
The double-aging strengthening effect of the γ’ phase in 945A nickel-based alloy was investigated. The double-aging treatment significantly improved the compressive yield stress. The sample after 8 h aging at 725 °C and 96 h at 800 °C exhibited the highest compressive yield stress of 1007 MPa, which greatly exceeded the original state of 229 MPa. The strengthening mechanism is mainly attributed to the Orowan strengthening mechanism. After double-aging treatment, high density γ’ phase precipitate was formed, which effectively improves the strength. The precipitate behavior and the strengthening mechanism of γ’ phase precipitates were clarified in detail.