Quantum networks have experienced rapid advancements in both theoretical and experimental domains over the last decade, making it increasingly important to understand their large-scale features from the viewpoint of statistical physics. This review paper discusses a fundamental question: how can entanglement be effectively and indirectly (e.g., through intermediate nodes) distributed between distant nodes in an imperfect quantum network, where the connections are only partially entangled and subject to quantum noise? We survey recent studies addressing this issue by drawing exact or approximate mappings to percolation theory, a branch of statistical physics centered on network connectivity. Notably, we show that the classical percolation frameworks do not uniquely define the network’s indirect connectivity. This realization leads to the emergence of an alternative theory called “concurrence percolation”, which uncovers a previously unrecognized quantum advantage that emerges at large scales, suggesting that quantum networks are more resilient than initially assumed within classical percolation contexts, offering refreshing insights into future quantum network design.

Quantum networks (QNs) exhibit stronger connectivity than predicted by classical percolation, yet the origin of this phenomenon remains unexplored. We apply a statistical physics model—concurrence percolation—to uncover the origin of stronger connectivity on hierarchical scale-free networks, the ( U , V ) flowers. These networks allow full analytical control over path connectivity through two adjustable path-length parameters, ≤ V . This precise control enables us to determine critical exponents well beyond current simulation limits, revealing that classical and concurrence percolations, while both satisfying the hyperscaling relation, fall into distinct universality classes. This distinction arises from how they “superpose” parallel, nonshortest path contributions into overall connectivity. Concurrence percolation, unlike its classical counterpart, is sensitive to nonshortest paths and shows higher resilience to detours as these paths lengthen. This enhanced resilience is also observed in real-world hierarchical, scale-free internet networks. Our findings highlight a crucial principle for QN design: When nonshortest paths are abundant, they notably enhance QN connectivity beyond what is achievable with classical percolation.

Quantum entanglement as a non-local correlation between particles is critical to the transmission of quantum information in quantum networks (QNs); the key challenge lies in establishing long-distance entanglement transmission between distant targets. This issue aligns with percolation theory, and as a result, an entanglement distribution scheme called “Classical Entanglement Percolation” (CEP) has been proposed. While this scheme provides an effective framework, “Quantum Entanglement Percolation” (QEP) indicates a lower percolation threshold through quantum preprocessing strategies, which will modify the network topology. Meanwhile, an emerging statistical theory known as “Concurrence Percolation” reveals the unique advantages of quantum networks, enabling entanglement transmission under lower conditions. It fundamentally belongs to a different universality class from classical percolation. Although these studies have made significant theoretical advancements, most are based on an idealized pure state network model. In practical applications, quantum states are often affected by thermal noise, resulting in mixed states. When these mixed states meet specific conditions, they can be transformed into pure states through quantum operations and further converted into singlets with a certain probability, thereby facilitating entanglement percolation in mixed state networks. This finding greatly broadens the application prospects of quantum networks. This review offers a comprehensive overview of the fundamental theories of quantum percolation and the latest cutting-edge research developments.

The evolution of connectivity in quantum networks under decoherence and link degradation is a central problem in quantum information, calling for further understanding of the nature of its transition during structural network degradation. By diluting each link with probability $1-\mathit{f}$, we focus on connectivity strength transitions in diluted hierarchical scale-free quantum networks, the $(u,v)$ flowers, which are analytically tractable through two adjustable path-length parameters, $u\le v$. Incorporating quantum concurrence percolation and comparing it with classical percolation, we analyze the transitions of critical thresholds for various values of f and v from analytical, numerical, and simulation perspectives. The results demonstrate that quantum percolation exhibits consistently lower critical thresholds than classical percolation, even under various topologies and dilution levels. Our work implies that quantum multipath entanglement provides an intrinsic compensatory mechanism against structural degradation and that the hierarchical scale-free topology contributes to the failure resistance and robustness of quantum networks with multipath coupling.