Nitrogen-doped (N-doped) graphene has been prepared by a simple one-step hydrothermal approach using hexamethylenetetramine (HMTA) as single carbon and nitrogen source. In this hydrothermal process, HMTA pyrolyzes at high temperature and the N-doped graphene subsequently self-assembles on the surface of MgO particles (formed by the Mg powder reacting with H2O) during which graphene synthesis and nitrogen doping are simultaneously achieved. The as-synthesized graphene with incorporation of nitrogen groups possesses unique structure including thin layer thickness, high surface area, mesopores and vacancies. These structural features and their synergistic effects could not only improve ions and electrons transportation with nanometer-scale diffusion distances but also promote the penetration of electrolyte. The N-doped graphene exhibits high reversible capacity, superior rate capability as well as long-term cycling stability, which demonstrate that the N-doped graphene with great potential to be an efficient electrode material. The experimental results provide a new hydrothermal route to synthesize N-doped graphene with potential application for advanced energy storage, as well as useful information to design new graphene materials.
It is difficult for beginners to learn and use amplicon analysis software because there are so many software tools to choose from, and all of them need multiple steps of operation. Herein, we provide a cross‐platform, open‐source, and community‐supported analysis pipeline EasyAmplicon. EasyAmplicon has most of the modules needed for an amplicon analysis, including data quality control, merging of paired‐end reads, dereplication, clustering or denoising, chimera detection, generation of feature tables, taxonomic diversity analysis, compositional analysis, biomarker discovery, and publication‐quality visualization. EasyAmplicon includes more than 30 cross‐platform modules and R packages commonly used in the field. All steps of the pipeline are integrated into RStudio, which reduces learning costs, keeps the flexibility of the analysis process, and facilitates personalized analysis. The pipeline is maintained and updated by the authors and editors of WeChat official account “Meta‐genome.” Our team will regularly release the latest tutorials both in Chinese and English, read the feedback from users, and provide help to them in the WeChat account and GitHub. The pipeline can be deployed on various platforms, and the installation time is less than half an hour. On an ordinary laptop, the whole analysis process for dozens of samples can be completed within 3 h. The pipeline is available at GitHub (https://github.com/YongxinLiu/EasyAmplicon) and Gitee (https://gitee.com/YongxinLiu/EasyAmplicon).
5 August 2016 in ACS Applied Materials & Interfaces
The intercalation of potassium ions into graphitic carbon materials has been demonstrated to be feasible while the electrochemical performance of the potassium-ion battery (PIB) is still unsatisfactory. More effort should be made to improve the specific capacity and achieve superior rate capability. Functional phosphorus and oxygen dual-doped graphene (PODG) is introduced as the anode for PIB, made by a thermal annealing method using triphenylphosphine and graphite oxide as precursors. It exhibits high specific capacity and ultra-long cycling stability, delivers a capacity of 474 mA h g−1 at 50 mA g−1 after 50 cycles and retains a capacity of 160 mA h g−1 at 2000 mA g−1 after 600 cycles. The superior electrochemical performance of PODG is mainly due to the large interlayer spacing caused by phosphorus and oxygen dual-doping, which facilitates potassium-ion insertion and extraction. Furthermore, the ultrathin and wrinkled features structure leads to a continuous and efficient supply of vacancies and defects for potassium storage.