In this study, starch and polycaprolactone (PCL), composite nanofibers were fabricated by co-axial needle electrospinning technique. Processing parameters such as polymer concentration, flow rate and voltage had a marked influence on the composite fiber diameter. Fourier transform infrared spectroscopy, scanning electron microscopy (SEM), mechanical and physical properties (such as density, viscosity and electrical conductivity) of the composite fibres were evaluated. Moreover, a cell culture test was performed in order to determine their cytotoxicity for wound dressing application. The effect of starch ratio in the solution on the properties and morphological structure of the fibers produced was presented. With lower starch concentration values, the fibers have greater ultimate tensile strength characteristic (mostly 4 and 5 wt%). According to SEM results, it can be figured out that the nanofibers fabricated have good spinnability and morphology. The mean diameter of the fibers is about 150 nm. According to results of cell culture study, the finding can be determined that the increase of starch in the fiber also increases the cell viability. Composite nanofibers of starch/PCL have been prepared using a co-axial needle electrospinning technique. PCL was successfully encapsulated within starch. Fiber formation was observed for different ratio of starch. With several test, analysis and measurement performed, some important parameters such as quality and effectuality of each fiber obtained for wound dressing applications were discussed in detail.
1 November 2016 in Materials Science and Engineering: C
The proximate composition of eleven walnut (Juglans regia L.) genotypes (28 ŞK 010, 28 ŞK 055, 28 ŞK 041, 28 ŞK 601, 28 ŞK 925, 28 ŞK 028, 28 ŞK 118, 28 ŞK 350, 28 ŞK 930, 28 ŞK 850, 28 ŞK 036) and three walnut cultivars (Şebin, Bilecik, Kaman 1) produced in Turkey were determined. The oil content of the samples ranged from 61.32 to 69.35%, corresponding to an energy value of approximately 710 kcal per 100 g of kernel. The protein content ranged from 10.58 to 18.19%, and the carbohydrate composition was between 9.05 and 18.92%. The ash content ranged from 1.53 to 1.99%, and the moisture content of the kernels was between 1.91 and 4.48% the oleic acid content of the oils ranged from 17.90 to 33.35% of the total fatty acids. The linoleic acid content ranged from 43.15 to 60.20%. The linolenic acid content ranged from 9.98 to 13.00%. The palmitic acid content was between 5.21 and 8.40%. Stearic acid ranged from 2.36 to 4.25%. Potassium was the major mineral in all the samples, ranging from 359.73 to 482.97 mg/100 g. Calcium was the next most abundant mineral, ranging from 109.45 to 335.97 mg/100 g, followed by magnesium, ranging from 126.01 to 165.15 mg/100 g
The objective of this study was to investigate the effect of magnesium (1 wt%) and aluminum (1 wt%) incorporation on the in vitro bioactivity and biodegradation behavior of 45S5 bioactive glasses synthesized from rice husk biogenic silica. The performance of biogenic silica-based samples was compared well with commercial silica-based counterparts. The in vitro biodegradation behavior of bioactive glasses was evaluated by the weight loss of samples and pH variation in the Tris buffer solution. Based on composition, bioglasses possessed different properties before and after simulated body fluid (SBF) immersion. The incorporation of magnesium (Mg) and aluminum (Al) enhanced the Vickers hardness of bioglasses. All the bioglasses showed the hydroxyapatite layer formation after SBF treatment as confirmed by the dissolution, FTIR, SEM and XRD analysis, however it was more prominent in the rice husk silica-based 45S5 bioglass. The biogenic silica seems to be a promising starting material for bioglass systems to be used in bone tissue engineering applications.