Solid-state electrolytes are widely anticipated to revitalize lithium-ion batteries with high energy density and safety. However, low ionic conductivity and high interfacial resistance at room temperature pose challenges for practical applications. This study combines the rigid oxide electrolyte LLZTO with the flexible polymer electrolyte poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) to achieve effective coupling of rigidity and flexibility. The semi-interpenetrating network structure endows the PEL composite solid electrolyte with excellent lithium-ion transport capabilities, resulting in an ionic conductivity of up to 5.1 × 10⁻⁴ S cm⁻¹ and lithium-ion transference number of 0.41. The assembled LiFePO₄/PEL/Li solid-state battery demonstrates an initial discharge capacity of 132 mAh g⁻¹ at a rate of 0.1 C. After 100 charge–discharge cycles, the capacity retention is 81%. This research provides a promising strategy for preparing composite solid electrolytes in solid-state lithium-ion batteries.

In this study, a ~20 μm (Ni,Pt)Al coating was applied to an IC21 substrate via electroplating followed by aluminizing. A thermal exposure test at 1100 °C in air was used to investigate the microstructure evolution and nanoindentation behavior of samples with and without coating. The experimental results show that the (Ni,Pt)Al coating caused a phase change from β-(Ni,Pt)Al to Ni₃Al, and the Topologically Close-Packed (TCP) phase at the interdiffusion zone grew larger after thermal exposure for 200 h at 1100 °C, while a layer of γ’ phase was formed on the surface of the IC21 substrate. The nanoindentation test indicated that the elastic modulus was reduced in both annealed samples (with and without coating), and after annealing the sample with coating had higher elastic modulus than the sample without coating. This result reveals that the coating effectively prevented the precipitation of refractory metal elements and the coarsening of the microstructure in the substrate, and thus shows that the coating had advantages not only in terms of improving the high-temperature oxidation properties of the substrate, but also played a significant role in improving the mechanical properties of the substrate.