Particulate Matter (PM) dramatically affects the well-being of a growing global population, particularly in urban areas. While air quality control is an important and pressing issue, particulate matter analysis typically focuses on size distribution and concentration, offering limited insights into chemical composition and pollutant sources. This study analyzes PM₁₀ samples collected from five air quality monitoring stations across the Piedmont region. Specifically, the two of the stations are located in the urban environment of Turin, a city known as one of Europe's most polluted cities. The analysis has been carried out using primarily Raman Spectroscopy (RS) to identify the main PM components, investigate the different PM compositions, and evaluate the chemical and seasonal variations. Scanning Electron Microscopy (SEM) equipped with an Energy Dispersion X-ray spectrophotometer (EDX) has also been used to obtain further information about the elemental composition and the size distribution. Amorphous carbon, nitrate salt, sulfate salt, iron oxides, and quartz are the main compounds found. The results of our study highlight significant differences in the chemical composition of PM₁₀, indicating variations in the sources and characteristics of PM. Notably, higher levels of nitrate and sulfate particles are linked respectively to cold and warm seasons. Whereas, amorphous carbon and iron oxides are associated with distinct geographic features at the sampling sites, such as traffic conditions. These findings emphasize the importance of understanding the different sources and characteristics of PM₁₀ to develop effective air pollution mitigation strategies in the Piedmont region.

Three measurement campaigns were conducted on the island of Culuccia (Sardinia, Italy) to evaluate particulate matter (PM) concentrations and the contribution of sea spray aerosol (SSA) across different seasons in a largely uncontaminated coastal environment. The goal is not only to analyze PM concentration in relation to meteorological parameters such as temperature, relative humidity (rH), and wind speed but also to provide a chemical analysis of SSA. The chemical composition of PM was determined using Raman spectroscopy and SEM-EDX, allowing for precise identification of individual particles. Results showed seasonal variations in PM composition, with sodium nitrate and sodium chloride prevalent in March and June and sulfates dominating in October. A correlation between the PM composition and meteorological parameters was observed according to the value of the deliquescence relative humidity (DRH), highlighting the reciprocal influence of rH and coarse and fine PM trends. This multi-technique approach offers valuable insights into the relative abundance of different PM compound classes based on the varying conditions for SSA formation. This enhances our understanding of the behavior of sea spray aerosol and other PM in natural coastal environments.