The popularity of 3D printing technology is rapidly increasing worldwide. It can be applied to metals, ceramics, composites, hybrids, and polymers. Three-dimensional printing has the potential to replace conventional manufacturing technologies because it is cost effective and environmentally friendly. This paper focuses on the influence of 3D printing conditions on the physical and mechanical properties of polylactic acid (PLA), poly(methyl methacrylate) (PMMA), and poly(ethylene terephthalate glycol-modified) (PETG) materials produced using Fused Deposition Modeling (FDM) technology. The impact of nozzle diameter, layer height, and printing temperature on the mechanical (i.e., bending stiffness and vibration damping) and physical (i.e., sound absorption and light transmission) properties of the studied polymer materials was investigated. It can be concluded that 3D printing conditions significantly influenced the structure and surface shape of the 3D-printed polymer samples and, consequently, their physical and mechanical properties. Therefore, it is essential to consider the type of filament used and the 3D printing conditions for specific 3D-printed material applications.
21 November 2011 in Journal of Applied Polymer Science
In this work, we examined the degradation behavior of isotactic poly(1-butene) (PB-1) under artificial aging and natural weathering conditions. PB-1 samples underwent accelerated aging through UV irradiation and natural weathering. Chemical and structural changes in the degraded samples were characterized using Fourier-transform infrared–attenuated total reflectance (FTIR–ATR) spectroscopy, surface analysis, and wide-angle X-ray scattering (WAXS). The mechanical properties were evaluated via tensile testing. FTIR–ATR analysis revealed the presence of carbonyl groups in the degraded samples, indicating oxidative degradation. Surface observations employing scanning electron microscopy (SEM) revealed the formation of surface cracks in both samples, with differing crack initiation mechanisms. The two aging methods affected the mechanical properties of the samples: artificial aging induced a gradual reduction in both tensile modulus and strength, whereas natural weathering engendered a marginal increment in modulus alongside diminished strength. Additionally, elongation-at-break value witnessed a marked decrease in both sample sets during the preliminary stages of degradation. This work employed accelerated time equivalent, obtained by juxtaposition of the values of carbonyl index during both artificial aging and natural weathering and their interpolation to determine the degradation rate and adequately to correlate the final properties of the aged PB-1. It was observed that surface morphology and mechanical attributes of degraded samples were subject to additional influences such as temperature, humidity, and precipitation during natural weathering. This research work provided significant insights into PB-1 degradation mechanisms and effect of different aging conditions on its performance. Graphical abstract