In response to the increasing global water demand and the pressing environmental challenges posed by climate change, the development of advanced wastewater treatment processes has become essential. This study introduces novel electrochemical technologies and examines the scalability of industrial-scale electrooxidation (EO) methods for wastewater treatment, focusing on simplifying processes and reducing operational costs. Focusing on the effective removal of key nutrients, specifically nitrogen and phosphorus, from wastewater, this review highlights recent advancements in electrode materials and innovative designs, such as high-performance metal oxides and carbon-based electrodes, that enhance efficiency and sustainability. Additionally, a comprehensive discussion covers a range of electrochemical methods, including electrocoagulation and electrooxidation, each evaluated for their effectiveness in nutrient removal. Unlike previous studies, this review not only examines nutrient removal efficiency, but also assesses the industrial applicability of these technologies through case studies, demonstrating their potential in municipal and industrial wastewater contexts. By advancing durable and cost-effective electrode materials, this study emphasizes the potential of electrochemical wastewater treatment technologies to address global water quality issues and promote environmental sustainability. Future research directions are identified with a focus on overcoming current limitations, such as high operational costs and electrode degradation, and positioning electrochemical treatment as a promising solution for sustainable water resource management on a larger scale.
The role of iron and aluminium in determining volatile solids reduction and odors from anaerobically digested, dewatered sludge cakes was evaluated from data collected from a variety of wastewater treatment plants. It was found that volatile solids reduction generally increased as the iron content of the sludge increased. It was also observed that odors increased with increasing iron. No correlation with aluminium or divalent cations was found. Based on these data it appears that the volatile solids reduction by anaerobic digestion is not useful for predicting the odors from anaerobically digested sludges.
Harnessing solar energy offers a sustainable alternative for powering electrolysis for green hydrogen production as well as wastewater treatment. The high costs and logistical challenges of electrolysis have resulted in limited widespread investigation and implementation of electrochemical technologies on an industrial scale. To overcome these challenges, this study designs and tests a new approach to chemical experiments and wastewater treatment research using a portable standalone open-source solar photovoltaic (PV)-powered station that can be located onsite at a wastewater treatment plant with unreliable electrical power. The experimental system is equipped with an energy monitoring data acquisition system. In addition, sensors enable real-time monitoring of gases—CO, CO2, CH4, H2, H2S, and NH3—along with temperature, humidity, and volatile organic compounds, enhancing safety during electrochemical experiments on wastewater, which may release hazardous gases. SAMA software was used to evaluate energy-sharing scenarios under different grid-connected conditions, and the system can operate off the power grid for 98% of the year in Ontario, Canada. The complete system was tested utilizing a laboratory-scale electrolyzer (electrodes of SS316L, Duplex 2205, titanium grade II and graphite) with electrolyte solutions of potassium hydroxide, sulfuric acid, and secondary wastewater effluent. The electrolytic cell specifically developed for testing electrode materials and wastewater showed a Faraday efficiency up to 95% and an energy efficiency of 55% at STP, demonstrating the potential for use of this technology in future work.