Sicily is a thick orogenic wedge formed by (1) the foreland (African) and its Sicilian orogen and (2) the thick-skinned, Calabrian–Peloritani wedge. The crust under central Sicily, from the Tyrrhenian margin to the coastline of the Sicily Channel, has been investigated by the multidisciplinary (SI.RI.PRO.) research project. The project dealt with the nature and thickness of the crust and depth and geometry of the Moho, which is essential in formulating subduction models and improving the knowledge of African and Tyrrhenian–European lithospheres. The results resolve features such as (1) the main orogenic wedge, (2) the very steep, NW–SE-trending regional monocline suggesting inflection of the foreland crust, (3) the deep Caltanissetta synform imaged, for the first time, to about 25 km, and (4) the top of the crystalline basement and the inferred crust–mantle boundary. The SI.RI.PRO. transect confirmed that the NNW-dipping, autochthonous Iblean platform of SE Sicily and its basement extends all the way into central Sicily. Further NW, towards the NNW end of the transect, a large uplift involves the Iblean platform and its underlying basement. The associated gravity anomaly is interpreted as the southern wedge edge of the Tyrrhenian mantle that splits the subducting Iblean–Pelagian (African) continental slab from an overlying synformal stack of allochthonous thrust sheets. Supplementary materials: Additional data are available at www.geolsoc.org.uk/SUP18594 .

Chemical composition in seawater of marine sediments, as well as the physical properties and chemical composition of soils, influence the phase behavior of natural gas hydrate by disturbing the hydrogen bond network in the water-rich phase before hydrate formation. In this article, some marine sediments samples, collected in National Antarctic Museum in Trieste, were analyzed and properties such as pH, conductivity, salinity, and concentration of main elements of water present in the sediments are reported. The results, obtained by inductively coupled plasma-mass spectrometry (ICP-MS) and ion chromatography (IC) analysis, show that the more abundant cation is sodium and, present in smaller quantities, but not negligible, are calcium, potassium, and magnesium, while the more abundant anion is chloride and sulfate is also appreciable. These results were successively used to determine the thermodynamic parameters and the effect on salinity of water on hydrates’ formation. Then, hydrate formation was experimentally tested using a small-scale apparatus, in the presence of two different porous media: a pure silica sand and a silica-based natural sand, coming from the Mediterranean seafloor. The results proved how the presence of further compounds, rather than silicon, as well as the heterogeneous grainsize and porosity, made this sand a weak thermodynamic and a strong kinetic inhibitor for the hydrate formation process.