In this paper, we presented an extended family of Miura-ori structures with programmable multi-step deformation via arraying and mirroring. We found that there is a competitive relationship between thickness gradient and structural gradient for these origami structures. Furthermore, we demonstrate that the multi-step deformation can be designed by altering the geometrical parametric and the order of these origami structures and the number of deformation stages will change with the change of the thickness gradient. Therefore, the current study can be used to construct novel origami metamaterials for engineering applications, such as energy absorbers for both light and heavy impacts.
Magnesium and its alloys have been widely studied as absorbable coronary stent materials. However, the rapid corrosion rate in the intravascular environment inhibits the application of magnesium-based stents. In order to endow magnesium-based stent with appropriate degradation rate and biocompatibility, a hydrophobic layer was constructed by in situ cyclic grafting 4,4′-diphenylmethane diisocyanate and aminopropyl-terminated polydimethylsiloxane on pure magnesium. SEM-EDS, X-ray photoelectron spectroscopy and water contact angle were detected to analyze the chemical composition of the layer. The amino groups were confirmed to be introduced on the surface which provide a platform for subsequent modification. The contact angle value of the modified surface is 132.1°, indicating a hydrophilic surface. The electrochemical measurements and immersion tests demonstrated that the hydrophobic layer significantly improved the anti-corrosion ability of the substrate. Besides, the biocompatibility of the hydrophobic surface was examined by platelet adhesion, cytocompatibility in vitro and subcutaneous implantation in vivo. Immunological and histological results indicated that the hydrophobic layer had excellent biocompatibility. Therefore, the presented study might be a promising method for the surface modification of biomedical magnesium-based stent.
In this paper, the mechanical properties of Nomex® paper coated with resin and composite Nomex® honeycomb sandwich structures (CNHSS) were obtained by tensile tests and flatwise tests respectively. The fundamental mechanical properties of the Nomex® paper were used as input materials parameters of finite element model generated at meso-scale level for the CNHSS, and the mechanical properties of CNHSSs were used to validate the numerical results. Based on the test and numerical results, the theoretical equations were modified to predict the flatwise compressive buckling strength and modulus of the CNHSS. The numerical and theoretical results clearly revealed that the CNHSS had two flatwise compressive elastic moduli. However, the flatwise test can only capture the second flatwise compressive elastic modulus due to manufacturing geometric defects of the cell walls. The numerical and test results showed that the manufacturing geometric defects of the cell walls showed little influence on the ultimate flatwise compressive strength. And the modified equation can predict the flatwise compressive buckling strength and modulus of the CNHSS with sufficient accuracy.