Novel optical gas-sensing materials for Au nanoparticle (NP)-modified ZnO nanorod (NR) arrays were fabricated using hydrothermal synthesis and magnetron sputtering on Si substrates. The optical performance of ZnO NR can be strongly modulated by the annealing temperature and Au sputtering time. With exposure to trace quantities of oxygen, the ultraviolet (UV) emission of the photoluminescence (PL) spectra of Au/ZnO samples at ~390 nm showed a large variation in intensity. Based on this mechanism, ZnO NR based oxygen gas sensing via PL spectra variation demonstrated a wide linear detection range of 10–100%, a high response value, and a 1% oxygen content sensitivity detection limit at 225 °C. This outstanding optical oxygen-sensing performance can be attributed to the large surface area to volume ratio, high crystal quality, and high UV emission efficiency of the Au NP-modified ZnO NR arrays. Density functional theory (DFT) simulation results confirmed that after the Au NPs modified the surface of the ZnO NR, the charge at the interface changed, and the structure of Au/ZnO had the lowest adsorption energy for oxygen molecules. These results suggest that Au NP-modified ZnO NR are promising for high-performance optical gas-sensing applications.

Laser ablation has been extensively studied by researchers due to its high precision, high efficiency processing capabilities, and wide range of application potentials. However, in a vacuum environment, due to the complexity of experimental conditions, specific application scenarios, and interdisciplinary interferences, more in-depth research on the ablation behavior of high-intensity lasers in vacuum is still insufficient. In response to such issues, experiments were conducted on titanium alloy perforation using a nanosecond laser in a vacuum environment. The variations in ablation depth and volume as functions of pulse energy, pulse number, and defocus were investigated. Both the depth and volume ablation efficiencies were calculated, and the three-dimensional morphology of the ablation holes was captured. Additionally, the ablation plume was observed to support the research conclusions. The results indicate that within the number of high-intensity laser pulses, the ablation depth per pulse can be increased by more than four times, and the average ablation volume per pulse can reach 0.97 µm³/µJ. The enhanced sputtering of molten material during the multi-pulse laser ablation process in a vacuum environment is identified as the primary factor contributing to the increased ablation efficiency. With the advancement of science and technology and the growing demand for applications, this research is crucial for the further development of fields such as space exploration and technology, advanced manufacturing technology, and basic scientific research.

This study systematically investigates the dynamic evolution of chemical regimes in pulsed coaxial dielectric barrier discharge (DBD) plasma under atmospheric pressure using mass spectrometry. An innovative real-time mass spectrometric monitoring methodology was established, enabling the dynamic tracking of the formation and consumption processes of key reactive species such as ozone (O₃) and nitrogen oxides (NO_x). Energy density was the critical parameter governing the evolution of gaseous chemical components, with a quantitative elucidation of the regulatory mechanisms of air flow rate and control voltage on plasma chemical regime transition kinetics. Experimental results revealed significant parametric correlations: Under a constant control voltage of 140 V, increasing the gas flow rate from 0.5 to 5.5 L/min prolonged the transition duration from O₃-NO_x coexistence regime to a NO_x-dominant regime from 408 s to 1210 s. Conversely, at a fixed flow rate of 3.5 L/min, elevating the control voltage from 120 V to 140 V accelerated this transition, reducing the required time from 2367 s to 718 s. Parametric sensitivity analysis demonstrated that control voltage exerts approximately 3.3 times greater influence on transition kinetics than flow rate variation. Through comprehensive analysis of the formation and consumption mechanisms of N, O, O₃, and NO_x species, we established a complete plasma chemical reaction network. This scheme provides fundamental insights into reaction pathways while offering practical optimization strategies for DBD systems. For aerospace applications, this work holds particular significance by demonstrating that the identified control parameters can be directly applied to plasma-assisted treatment of propellant wastewater at launch sites, where the efficient removal of nitrogen-containing pollutants is crucial. These findings advance both the fundamental understanding of atmospheric-pressure plasma chemistry and the engineering applications of plasma-based environmental remediation technologies in aerospace operations.