The element geochemical behavior and provenance of marine sediments are of significance to understanding the oceanic material cycle. Here, we tested the grain size and major and trace elements of 35 surface sediments in the offshore area of Sierra Leone, analyzed the content characteristics and controlling factors of the elements, discussed the material source of the sediments, and made a comparative study with the sediments in the offshore area of China. The results show that sandy silt is the main sediment type in the research area, and the average sediment mean grain size (Mz) is 4.15Φ. The content of Ca in the samples is the highest among the major elements (except Si), with an average of 5.1%. The content of Sr is the highest among the trace elements (except Ti, P, and Mn), with an average of 378.2 μg/g. The results of correlation analysis and factor analysis show that there are three main sources of sediments in the research area, namely, terrigenous weathering products, ilmenite-dominated ore, and oceanic biochemical substances. Compared with the sediments in China offshore, the sediments in the study area are more affected by marine biochemistry and have special ore input characteristics.