The escalating issue of phenol-containing wastewater necessitates the development of efficient and sustainable treatment methods. In this context, we present a novel composite photocatalyst comprising ZnFe2O4 (ZFO) nanoparticles supported on nanocellulose (NC), aimed at addressing this environmental challenge. The synthesis involved a facile hydrothermal method followed by the impregnation of ZFO nanoparticles onto the NC matrix. The morphology and structure of ZFO, NC, and ZFO/NC were investigated by TEM, SEM-EDX, UV–vis, FT-IR, XRD, and XPS analyses. ZFO, as a weakly magnetic semiconductor catalytic material, was utilized in photocatalytic experiments under magnetic field conditions. By controlling the electron spin states through the magnetic field, electron–hole recombination was suppressed, resulting in improved photocatalytic performance. The results demonstrated that 43% and 76% degradation was achieved after 120 min of irradiation due to ZFO and 0.5ZFO/NC treatment. Furthermore, the composite 0.5ZFO/NC demonstrated the highest photocatalytic efficiency, showing promising recyclability by maintaining its activity after three cycles of use. This study underscores the potential of the ZFO/NC composite for sustainable wastewater treatment, offering a promising avenue for environmental remediation.
In deep-hole boring processes, boring bars with a large length-to-diameter ratio are typically employed. However, excessive overhang significantly reduces the boring bar’s stiffness, inducing vibrational effects that severely degrade machining precision and surface quality. To address this, the research objective is to suppress vibrations using a tunable-parameter boring bar. This paper proposes a novel Tunable Dynamic Vibration Absorber (TDVA) boring bar and designs its fundamental parameters. Based on the derived dynamic model, the vibration characteristics of the proposed boring bar are analyzed, revealing the variation in damping performance under different excitation frequencies. By establishing the relationship between TDVA stiffness, damping, and the axial compression of rubber bushings, optimal parameter combinations can be precisely identified for specific excitation frequencies. Ultimately, adjusting the TDVA’s axial compression displacement (0.1–0.5 mm) significantly expands the effective machining frequency range compared to conventional designs while maintaining operational reliability. This study proposes a novel Tunable Dynamic Vibration Absorber (TDVA) that innovatively integrates axial compression to achieve coupled stiffness and damping adjustments, addressing the rigidity–adaptability trade-off in deep-hole boring tools.
In deep-hole boring processes, boring bars with a large length-to-diameter ratio are typically employed. However, excessive overhang significantly reduces the boring bar’s stiffness, inducing vibrational effects that severely degrade machining precision and surface quality. To address this, the research objective is to suppress vibrations using a tunable-parameter boring bar. This paper proposes a novel Tunable Dynamic Vibration Absorber (TDVA) boring bar and designs its fundamental parameters. Based on the derived dynamic model, the vibration characteristics of the proposed boring bar are analyzed, revealing the variation in damping performance under different excitation frequencies. By establishing the relationship between TDVA stiffness, damping, and the axial compression of rubber bushings, optimal parameter combinations can be precisely identified for specific excitation frequencies. Ultimately, adjusting the TDVA’s axial compression displacement (0.1–0.5 mm) achieves a 22% expansion in the effective machining frequency range.
To overcome the limitations imposed by the intermittent nature of sunlight in photocatalytic applications, this research constructs a round-the-clock purification system. We integrated an optimized S-scheme CoFe2O4/BiVO4 (CFO/BV) heterojunction (synthesized via ultrasonic self-assembly at a 0.5:0.5 ratio) with a thermal energy storage (TES) unit consisting of SiO2-encapsulated Na2SO4·10H2O phase change materials (PCMs). Comprehensive characterization techniques, including XRD, HRTEM, UV-Vis DRS, EPR, and DSC, confirmed the successful formation of the interface, a broadened visible-light response (λ > 650 nm), efficient radical production, and a high latent heat storage capacity (>200 J/g). Under simulated solar irradiation, the composite exhibited superior performance, degrading 98% of the Rhodamine B within 6 h (k = 0.00994 min−1), significantly surpassing single-component counterparts. More importantly, during the subsequent 12 h dark period, the heat released from the PCM maintained the reaction temperature above 35 °C, driving a 64% degradation efficiency via a thermocatalytic pathway. The system demonstrated robust stability (>90% efficiency after five cycles), excellent magnetic recoverability (98%), and high tolerance to saline textile wastewater (<10% activity loss). Furthermore, Life Cycle Assessment (LCA) indicated a 40% reduction in energy consumption compared to conventional UV/TiO2 processes, highlighting a sustainable strategy for continuous wastewater remediation through synergistic photocatalysis and thermocatalysis.