Marcelino Maneiro

Prof. Marcelino Maneiro

Universidade de Santiago de Compostela
orcid

Research Focus & Metrics

Academic Career Length

30Years (1997-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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20 December 2004 in Dalton Transactions
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Journal Article
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RPRosa Pedrido
Rosa Pedrido
MBManuel R. Bermejo
Manuel R. Bermejo
MRM. José Romero
M. José Romero
Miguel Vázquez LópezMiguel Vázquez López
Miguel Vázquez López
AGAna M. González-Noya
Ana M. González-Noya
MFM. Isabel Fernández
M. Isabel Fernández
In this paper we describe the electrochemical synthesis and characterization of new neutral manganese, iron, cobalt, nickel, copper, zinc, cadmium and lead complexes with the ligand bis(4-N-methylthiosemicarbazone)-2,6-diacetylpyridine, H4DAPTsz-Me. X-Ray structures of [Mn(H2DAPTsz-Me)(EtOH)2] 1, [Pb(H2DAPTsz-Me)] 3 and [Zn(H2DAPTsz-Me)]2·EtOH·2H2O 4, were also determined. In these complexes the ligand behaves as bis-deprotonated and SNNNS pentadentate. In the manganese complex the metal is heptacoordinated, in a distorted pentagonal-bipyramidal environment, with the N3S2 donor set of the ligand in the pentagonal girdle and two solvent molecules occupying the axial positions. In the lead complex 3 the metal is pentacoordinated, bound exclusively to the five donor atoms of the ligand, as a consequence of the existence of “inert pair effect”. The bishelical zinc complex 4 shows each zinc atom with different coordination geometry, one octahedrally six-coordinate while the other is distorted tetrahedrally four-coordinate.

1 January 2000 in Polyhedron
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Journal Article
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Jesus Sanmartín-MatalobosJesus Sanmartín-Matalobos
Jesus Sanmartín-Matalobos
MBManuel R. Bermejo
Manuel R. Bermejo
Ana M. Garcia-DeibeAna M. Garcia-Deibe
Ana M. Garcia-Deibe
Marcelino ManeiroMarcelino Maneiro
Marcelino Maneiro
CLCarmen Lage
Carmen Lage
ACAntonio Costa-Filho
Antonio Costa-Filho

1 January 2000 in Polyhedron
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Journal Article
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Marcelino ManeiroMarcelino Maneiro
Marcelino Maneiro
MBM.R Bermejo
M.R Bermejo
ASA Sousa
A Sousa
Matilde FondoMatilde Fondo
Matilde Fondo
AGA.M González
A.M González
CMCharles A McAuliffe
Charles A McAuliffe

25 February 2003 in New Journal of Chemistry
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Journal Article
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Marcelino ManeiroMarcelino Maneiro
Marcelino Maneiro
MBManuel R. Bermejo
Manuel R. Bermejo
MFM. Isabel Fernández
M. Isabel Fernández
EGEsther Gómez-Fórneas
Esther Gómez-Fórneas
AGAna M. González-Noya
Ana M. González-Noya
ATAlexei M. Tyryshkin
Alexei M. Tyryshkin
New manganese(II) and manganese(III) complexes of substituted N,N′-bis(salicylidene)-1,2-diimino-2-methylethane have been prepared and characterized. Elemental analysis, IR and EPR spectroscopies, mass spectrometry, magnetic measurements and the study of their redox properties have confirmed their respective formulae as MnIIL(H2O)2 and MnIIIL(H2O)n(ClO4). Electron-withdrawing substituents on the phenyl rings of the ligand stabilize the oxidation state (II) for manganese, but the electron-donating substituents on the Schiff bases are those that lead to Mn(III) complexes, which behave as efficient peroxidase mimics in the presence of the water-soluble trap ABTS. The rate of peroxidase activity of the present complexes is significantly higher than that of other series of Mn-Schiff base compounds, probably due to their versatility in adopting in solution a structure that allows the coordination of the hydrogen peroxide substrate molecule to the manganese.

20 June 2003 in Chemical Communications
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Miguel Vázquez LópezMiguel Vázquez López
Miguel Vázquez López
Angelo TagliettiAngelo Taglietti
Angelo Taglietti
DGDante Gatteschi
Dante Gatteschi
Lorenzo SoraceLorenzo Sorace
Lorenzo Sorace
CSClaudio Sangregorio
Claudio Sangregorio
MBManuel R. Bermejo
Manuel R. Bermejo
The neutral dinuclear dihelicate [Cu2(L)2]·2CH3CN (1) forms a unique 3D network in the solid state due to π-stacking interactions, which are responsible for intermolecular antiferromagnetic coupling between Cu(II) ions.

8 August 2007 in European Journal of Inorganic Chemistry
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Journal Article
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MBManuel R. Bermejo
Manuel R. Bermejo
MFM. Isabel Fernández
M. Isabel Fernández
EGEsther Gómez‐Fórneas
Esther Gómez‐Fórneas
AGAna González‐Noya
Ana González‐Noya
Marcelino ManeiroMarcelino Maneiro
Marcelino Maneiro
MRM. Jesús Rodríguez
M. Jesús Rodríguez