Among the most promising areas of research, cellulose-based electrochemical sensors stand out for their intrinsic properties such as abundance, biocompatibility, and versatility. This review is concerned with the integration and application of cellulose-derived materials in electrochemical sensors, pointing out improvements in sensitivity, selectivity, stability, and functionality for a wide variety of applications. The most relevant developments on cellulose-based sensors have been concentrated on nanocellulose composite synthesis, advanced cellulose modification, and the successful embedding in wearable technologies, medical diagnostics, and environmental monitoring. Considering these, it is worth mentioning that significant challenges still need to be overcome regarding the scalability of production, selectivity improvement, and long-term stability under real operational conditions. Future research efforts will concern the union of cellulose-based sensors with the Internet of Things (IoT) and artificial intelligence (AI) toward wiser and more sustainable health and environmental solutions. Correspondingly, this work puts cellulose in the front line among the most perspective materials for enabling the development of eco-friendly and high-performance sensing technologies.

The search for sustainable and efficient remediation techniques is required to control increasing environmental pollution caused by synthetic dyes, heavy metal ions, and other harmful pollutants. From this point of view, natural polymers like chitosan, cellulose, lignin, and pectin have been found highly promising due to their biodegradability, availability, and possibility of chemical functionalization. Natural polymers possess inherent adsorption properties that can be further enhanced by cross-linking and surface activation. This review discusses the main properties, adsorption mechanisms, and functional groups such as hydroxyl, carboxyl, and amino groups responsible for pollutant sequestration. The paper also emphasizes the effectiveness of natural polymers in removing heavy metals and dyes from wastewater and discusses recent advances in polymer modifications, including ionic crosslinking and grafting. This study underlines the ecological potential of natural polymer-based adsorbents in the treatment of wastewater and the protection of the environment as a sustainable solution to pollution challenges.

In this study, the fabrication of magnetic hemicellulosic composite microspheres and the adsorption of copper ions are explored. The microspheres were prepared by the micro-emulsion technique, using Fe₃O₄ nanoparticles and hemicellulose extracted from wheat straw with the ionic liquid B[mim]Cl as a solvent. Fe₃O₄ nanoparticles, synthesized through coprecipitation, were evenly encapsulated within the hemicellulosic microspheres. The Fe₃O₄ nanoparticles measured 10–15 nm in size, while the microspheres had an average diameter of about 20 μm and displayed a saturation magnetization of 35.95 emu/g. The optimal conditions for copper adsorption by the microspheres were found to be a pH of 5.0, a temperature of 323 K, and an initial copper ion concentration of 80 mg/L, resulting in an adsorption capacity of 85.65 mg/g after 24 h. The adsorption kinetics followed a pseudo-second-order model, and the Langmuir isotherm suggested a monomolecular layer adsorption mechanism, with a theoretical maximum capacity of 149.25 mg/g. In summary, the magnetic hemicellulosic microspheres exhibited considerable adsorption potential and favorable recycling capabilities for copper ions.