Microplastics (MPs) can serve as vectors for heavy metals in aquatic environments; however, the adsorption behavior of MPs on multiple heavy metal systems is still unclear. This study investigated the adsorption characteristics of biodegradable poly (butylene succinate) (PBS) for cadmium (Cd(II)) and arsenic (As(III)) in both single and binary systems. Adsorption isotherms were studied using the Linear, Langmuir, and Freundlich models, and further analysis of MPs adsorption characteristics was conducted using site energy distribution theory and density functional theory. The results indicate that the maximum adsorption capacities of PBS for Cd(II) and As(III) are 2.997 mg/g and 2.606 mg/g, respectively, with the Freundlich model providing the best fit, suggesting multilayer adsorption on heterogeneous sites. As(III) has a higher adsorption affinity for PBS than Cd(II), with a binding energy of −11.219 kcal/mol. Additionally, the adsorption mechanisms of Cd(II) and As(III) on PBS include electrostatic interactions and surface complexation, with the primary adsorption sites at the C=O of the carboxyl group and the hydroxyl group. The comprehension of interfacial interactions between biodegradable plastics and heavy metals is facilitated by a combination of theoretical calculations and experimental investigations.
TB18 is a newly developed high-strength metastable β-titanium alloy, commonly used in aerospace structural materials, which demands high mechanical performance. By altering the alloy’s microstructure, heat treatment can affect its mechanical characteristics. The alloy was solution treated for one to four hours at 870 °C in order to examine the impact of solution treatment duration. Using X-ray diffraction (XRD) and scanning electron microscopy (SEM), the effects of solution treatment time on the β-phase grain size and its effect on stress distribution during tensile testing were examined. The findings showed that stress concentration during the tensile process was successfully decreased by refining the β-phase grain size. Sample solutions treated for two hours at 870 °C were then aged at various temperatures (510 °C, 520 °C, 530 °C, and 540 °C) to examine the impact of aging temperature. While the mass proportion of the α-phase first climbed and subsequently declined, reaching its maximum at 530 °C, the size of the α-phase increased monotonically as the aging temperature increased. The varies of mass fraction is associated with how the aging temperature affects α-phase nucleation. Tensile studies on TB18 alloy aged at various temperatures showed that while the alloy’s ductility reduced, its strength increased as the aging temperature rose. The Hall-Petch relationship explains this tendency.