• Introducing a facile sonochemical approach for the efficient preparation of new photocatalytic nanocomposites (Dy2O3-SiO2). • Remarkable effect of SiO2 on improving photocatalytic performance of Dy2O3. • Excellent photocatalytic performance of sonochemically fabricated Dy2O3-SiO2 nanocomposite in removal of organic pollutants under sunlight, for the first time. • Enhanced optical absorption and having a high specific surface area were responsible for enhanced photocatalytic performance. • Significant effect of sonication on the synthesis of high-performance binary Dy2O3-SiO2 nanophotocatalys.
Water contamination has turned into a critical global concern that menaces the entire biosphere and has a notable effect on the lives of living beings and humans. As a proper and environmentally friendly solution, visible-light photocatalysis technology has been offered for water contamination removal. There is a strong interest in the design of the efficient catalytic materials that are photoactive with the aid of visible light. Herein, to fabricate a highly efficient photocatalyst for removal of organic pollution in water, a facile and swift sonochemical route employed for creation of the spindle shaped PbWO4 nanostructure with the aid of an environmentally friendly capping agent (maltose) for the first time. To optimize the efficiency, dimension and structure of lead tungstate, various effective factors such as time, dose of precursors, power of ultrasound waves and kind of capping agents were altered. The attributes of PbWO4 samples were examined with the aid of diverse identification techniques. The produced lead tungstate samples in role of visible-light photocatalyst were applied to remove organic pollution in water. The kinds of pollutants, dose and type of catalyst were examined as notable factors in the capability to eliminate contaminants. Very favorable catalytic yield and durability were demonstrated by spindle-shaped PbWO4 nanostructure (produced at power of 60 W for 10 min and with usage of maltose). Usage of ultrasonic irradiation could bring to improvement of catalytic yield of PbWO4 to 93%. Overall, the outcomes could introduce the spindle-shaped PbWO4 nanostructure as an efficient substance for eliminating water contamination under visible light.
Waste from construction and demolition (also known as CDW) is one of the most harmful environmental issues. This study's primary goal is to produce new mortar and brick materials from recycled concrete powder (RCP) and recycled brick powder (RBP), two of the most popular CDW. Geopolymeric mortar and brick samples were produced by passing RCP and RBP through sieve No. 50 (with sand filler if necessary) and combining them with an alkaline solution made of water glass (WG) and NaOH. In this study, the mixture was then cured for three days at 80 °C in an oven. The effects of filler, RBP amount, WG amount, and the concentration of NaOH alkaline solution on the samples’ strength were examined. Additionally, XRF and SEM/XRD tests were performed to verify the materials' composition and microstructure. The mechanical strength of the samples showed an increase with the increase of RCP values, so the brick sample with filler showed the highest compressive strength, measuring 59.53 MPa. The study's samples exhibited strong mechanical properties. Additionally, all of the bricks' water absorption fell within the standard range. In summary, according to different standards, both waste concrete and waste brick can be used to produce geopolymer materials especially bricks for construction and paving purposes.