A novel approach toward the production of multifunctional printed technical textiles is reported. Three different metal oxides nanoparticles including titanium dioxide, magnesium oxide, and zinc oxide were prepared and characterized. Both natural wool and synthetic acrylic fibers were pretreated with the prepared metal oxide nanoparticles followed by printing using polylactic acid based paste containing acid or basic dyestuffs. Another route was applied via post-treatment of the targeted fabrics with the metal oxide nanoparticles after running the printing process. The color strength (K/S) and colorfastness properties of pretreated and post-treated printed fabrics were evaluated and compared with untreated printed fabrics. The presence of nanoparticles on a fabric surface during the coating process was found to significantly increase the color strength value of the coated textile substrates. The increased K/S value depended mainly on the nature and concentration of the applied metal oxide, as well as the nature of colorant and fabric. In addition, the applied metal oxide nanoparticles imparted the printed fabrics with good antibacterial activity, high ultraviolet protection, photocatalytic self-cleaning, and improved colorfastness properties. Those results suggest that the applied metal oxide-based nanoparticles could introduce ideal multifunctional prints for garments.

For the detection of Cd(II) in aquatic media, a novel dicyanomethylene dihydrofuran hydrazone(DCDHFH)-based colorimetric chemosensor was developed. DCDHFH was prepared by an azo-coupling process involving the diazonium chloride of 2, 4-dichloroaniline and a dicyanomethylene dihydrofuran heterocyclic moiety bearing an active methyl group. The DCDHFH chromophore showed strong solvatochromism depending on solvent polarity due to electronic delocalization. The pH sensory effects of the DCDHFH chromophore were also explored. DCDHFH could be used to identify Cd(II) in the presence of other competitive metals, as indicated by variations in color and absorbance spectra. In the presence of cadmium ions, the synthesized DCDHFH probe with hydrazone recognition moiety exhibited a significant sensitivity and selectivity to cadmium ions at the ppm concentration level (10–250 ppm). A DCDHFH-immobilized paper test strip was also prepared and effectively used for the detection of cadmium in aqueous media at various concentrations. According to CIE Lab’s criteria, colorimetric strength (K/S), and the UV–Vis absorbance spectra, the cadmium detection abilities of the DCDHFH-immobilized paper strips were evaluated. The optimal pH range for the determination of Cd(II) was monitored in the area of 5.5–6.3, with a fast chromogenic change from yellow to red relying on the Cd(II) concentration. The deposition of dicyanomethylene dihydrofuran hydrazone onto the paper strip’s surface was studied by scanning electron microscopy (SEM).