The joint estimation of groundwater contaminant source characteristics and hydraulic conductivity is of great significance for reactive contaminant transport models in heterogeneous subsurface media. The accurate determination of the sorption parameters of such contaminants is also a key prerequisite for estimating the parameters of the groundwater system. In this study, to investigate the impact of the sorption parameter field on the accuracy of hydraulic conductivity and source characteristics estimation, numerical experiments were conducted in a synthetic aquifer considering the contaminant sorption process in groundwater models with varying sorption parameter settings. Iterative local updating ensemble smoother with geometric inflation selection (ILUES-GEO) was employed to assimilate hydraulic head and contaminant concentration data to jointly estimate the contaminant source information and hydraulic conductivity in a heterogeneous aquifer. The results indicated that the ILUES-GEO successfully recovers contaminant source information simultaneously with hydraulic conductivity, and its performance improves as more accurate sorption parameters are introduced. Furthermore, the influence of the ILUES algorithm parameters and ensemble size is investigated to improve the estimation accuracy. Additionally, the characterization of contaminant sources and hydraulic conductivity fields is influenced by the number and locations of measurements. This study can help to understand the significance of sorption parameter setting for the joint estimation of reactive contaminant source and hydraulic parameters.

Sustainable groundwater resource management necessitates dependable and precise predictions of groundwater head fields under fluctuating climatic conditions. The substitution of original simulation models with efficient surrogates presents a challenge in simultaneously accounting for correlations among multiple time series outputs and maintaining overall prediction accuracy. This study develops a novel surrogate modelling approach, DSCNN-GRU, incorporating a deep separable convolutional neural network (DSCNN) and a gated recurrent unit (GRU), to efficiently capture temporal and spatial variations in groundwater head fields from transient groundwater flow models using input hydraulic conductivity field data. The applicability and performance of the proposed method are evaluated for predicting groundwater head fields in a practical research area under three scenarios with different hydraulic conductivity fields. The performance of the DSCNN-GRU model is compared to the traditional convolutional neural network (CNN), CNN-LSTM, and DSCNN-LSTM models to further test its applicability. The numerical study demonstrates that optimizing hyperparameters can result in reasonably accurate performance of the proposed model, and the “simplest” DSCNN-GRU outperforms CNN, CNN-LSTM, and DSCNN-LSTM in both prediction accuracy and time-to-solution.