Most of the current studies rely on simulated brine corrosion environments and lack long-term investigations into concrete corrosion damage evolution under actual corrosive conditions. In this paper, high-performance concrete (HPC) with various mix ratios is designed in the context of the Qinghai Salt Lake region in China, and the evolution of corrosion damage of HPC with different water–binder ratios (W/B) and different fly ash (FA) admixtures under long-term field exposure conditions is obtained by testing the ultrasonic velocity and strengths of the HPC in the field exposure of the HPC in the Qinghai Salt Lake region. The results show that the corrosion resistance of HPC is related to its water–binder ratio and mineral admixture type and dosage under the exposure of 8 years in Qinghai Salt Lake area. HPC with a fly ash dosage of 15–35% and silica fume dosage of 10% exhibits better corrosion resistance when the water–binder ratio (W/B) is between 0.24 and 0.38. The dependence relationship between the corrosion resistance coefficient of HPC and the relative dynamic elastic modulus (E_rd) and 28 d standard maintenance strength was also established. The E_rd of HPC with a corrosion resistance coefficient of 0.80 or above was 0.73–0.93, not 0.60, which provides an important experimental basis for determining the corrosion damage index of HPC in the high-saline brine environment of the salt lake.

Salt lakes and the surrounding saline soils distributed across northwestern China and Inner Mongolia impose severe physicochemical corrosion on cement-based concrete. Understanding the corrosion products and mechanisms are crucial scientific and technological factors in ensuring the durability and service life of concrete structures in these regions. In this study, various analytical techniques—including X-ray diffraction, thermogravimetric–differential thermal analysis, X-ray fluorescence, and scanning electron microscopy coupled with energy-dispersive spectroscopy—were employed to systematically analyze the corrosion products of ordinary Portland cement (OPC) and high-performance concrete (HPC) specimens after eight years of field exposure in the Qarhan Salt Lake area of Qinghai. The study provided an in-depth understanding of the physicochemical corrosion mechanisms involved. The results showed that, after eight years of exposure, the corrosion products comprised both physical corrosion products (primarily sodium chloride crystals), and chemical corrosion products (associated with chloride, sulfate, and magnesium salt attacks). A strong correlation could be observed between the chemical corrosion products and the strength grade of the concrete. In C25 OPC, the detected corrosion products included gypsum, monosulfate-type calcium sulfoaluminate (AFm), Friedel’s salt, chloro-ettringite, brucite, magnesium oxychloride hydrate 318, calcium carbonate, potassium chloride, and sodium chloride. In C60 HPC, the identified corrosion products included Kuzel’s salt, Friedel’s salt, chloro-ettringite, brucite, calcium carbonate, potassium chloride, and sodium chloride. Among them, sulfate-induced corrosion led to the formation of gypsum and AFm, whereas chloride-induced corrosion resulted in chloro-ettringite and Friedel’s salt. Magnesium salt corrosion contributed to the formation of brucite and magnesium oxychloride hydrate 318, with Kuzel’s salt emerging as a co-corrosion product of chloride and sulfate attacks. Furthermore, a conversion phenomenon was evident between the sulfate and chloride corrosion products, which was closely linked to the internal chloride ion concentration in the concrete. As the chloride ion concentration increased, the transformation sequence of sulfate corrosion products occurred in the following order: AFm → Kuzel’s salt → Friedel’s salt → chloro-ettringite. There was a gradual increase in chloride ion content within these corrosion products. This investigation into concrete durability in salt-lake ecosystems offers technological guidance for infrastructure development and material specification in hyper-saline environments.