A mesoporous ZnIn2S4 photocatalyst shows notable activity for photoreforming of PLA, PET and PU to generate small organic chemicals and H2 fuel under simulated sunlight at room temperature.
A biomimetic catalytic approach for the aerobic oxidation of C–sp(3)–H bonds using galactose oxidase model compound was developed. EPR showed that the CuI-radical intermediate species was critical for O2 activation.