Foamed concrete contains numerous pores inside the material, and these pores are a significant factor determining the material characteristics. In particular, the pore distribution characteristics of foamed concrete significantly affect its thermal and mechanical properties. Therefore, an appropriate investigation is necessary for a more detailed understanding of foamed concrete. Here, a set of foamed concrete samples with different densities is used in order to investigate the density effects on the pore characteristics, as well as the physical properties of the materials. The pore distribution characteristics of these samples are investigated using an X-ray micro-computed tomography (micro-CT) imaging technique with probabilistic and quantitative methods. Using these methods, the anisotropy, the pore circularity factor and the relative density of cell thickness are examined. The thermal (thermal conductivity) and mechanical (directional modulus and strength) properties of each foamed specimen are computed using numerical simulations and compared with experimental results. From the obtained results, the effects of the pore sizes and shapes on the local and global properties of the foamed concrete are examined for developing advanced foamed concrete with lower thermal conductivity by minimizing the strength reduction.
A complex symmetry-breaking current instability in doped semiconductors induced by low-temperature impact ionization breakdown is investigated. We present computer simulations revealing the dynamics of the self-organized formation of multiple current filaments in n-GaAs Corbino disks, i.e., samples with concentric circular contacts. Our results explain the nascence of a filament in terms of two consecutive stages: a radially symmetric impact ionization front spreading from the inner contact becomes unstable and breaks up into a number of streamers evolving into prefilaments. With rising current, competition between those prefilaments takes place due to the global coupling via the load resistance. Only a small number of these survive and grow into fully developed filaments. Using the applied bias as a control parameter we find multistability and hysteresis, with jumps in the current-voltage characteristic caused by the spontaneous formation of additional filaments in the Corbino disk.
Low‐vacuum scanning electron microscopy (low‐vacuum SEM) is widely used for different applications, such as the investigation of noncoated specimen or the observation of biological materials, which are not stable to high vacuum. In this study, the combination of mineral building materials (concrete or clay plaster) with a biological composite (fungal mycelium composite) by using low‐vacuum SEM was investigated.Fungal biotechnology is increasingly gaining prominence in addressing the challenges of sustainability transformation. The construction industry is one of the biggest contributors to the climate crises and, therefore, can highly profit from applications based on regenerative fungal materials. In this work, a fungal mycelium composite is used as alternative to conventional insulating materials like Styrofoam. However, to adapt bio‐based products to the construction industry, investigations, optimisations and adaptations to existing solutions are needed. This paper examines the compatibility between fungal mycelium materials with mineral‐based materials to demonstrate basic feasibility. For this purpose, fresh and hardened concrete specimens as well as clay plaster samples are combined with growing mycelium from the tinder fungus Fomes fomentarius. The contact zone between the mycelium composite and the mineral building materials is examined by scanning electron microscopy (SEM).The combination of these materials proves to be feasible in general. The use of hardened concrete or clay with living mycelium composite appears to be the favoured variant, as the hyphae can grow into the surface of the building material and thus a layered structure with a stable connection is formed.In order to work with the combination of low‐density organic materials and higher‐density inorganic materials simultaneously, low‐vacuum SEM offers a suitable method to deliver results with reduced effort in preparation while maintaining high capture and magnification quality. Not only are image recordings possible with SE and BSE, but EDX measurements can also be carried out quickly without the influence of a coating. Depending on the signal used, as well as the magnification, image‐recording strategies must be adapted. Especially when using SE, an image‐integration method was used to reduce the build‐up of point charges from the electron beam, which damages the mycelial hyphae. Additionally using different signals during image capture is recommended to confirm acquired information, avoiding misinterpretations.
1 February 2023 in Journal of Materials in Civil Engineering
Solar thermal energy is a technology that collects radiant energy from the sun to generate heat or electricity. Thermal energy storage is required to compensate for the solar thermal energy variations across time scales, and a popular strategy is storing thermal energy in hot water tanks. Due to superior strength and durability, ultrahigh-performance concrete (UHPC) is exploited to construct such water tanks for applications at 200°C. Therefore, the mechanical strength and microstructure of UHPC after long-term temperature-pressure load (autoclaving) is studied. The compressive strength of UHPC can stay robust due to the accelerated formation of hydrates, while the flexural strength is vulnerable to long-term autoclaving due to the transformation of amorphous calcium silicate hydrate (C-S-H) to more ordered phases. The main hydrates in autoclaved samples are poorly crystallized C-S-H, hydroxylellestadite, and hydrogarnet. The porosity of autoclaved samples is not strictly related to the mechanical strength, and the influence of hydrate assemblage outweighs that of porosity on mechanical strength after long-term autoclaving. The partial replacement of cement by limestone powder can decrease crystalline hydrates and increase poorly crystallized C-S-H, which densifies the microstructure and enhances the mechanical strength. However, excessive poorly crystallized C-S-H aggravates the thermal mismatch between the matrix and quartz aggregates after autoclaved samples cool to room temperature, leading to interstice in matrix-quartz interfaces and, thus, reduced mechanical strength. Therefore, an appropriate addition of limestone powder is required to induce the hydrate assemblage with appropriate poorly crystallized C-S-H, ensuring durable UHPC structures under autoclaving.