Nanocellulose, including cellulose nanofibers (CNFs), cellulose nanocrystals (CNCs), and bacterial nanocellulose (BNC), represents a promising class of bio-based nanomaterials derived from natural sources. These materials, derived from plant-based cellulose, are characterized by exceptional mechanical strength, high surface area, biodegradability, and the ability to form stable nanoparticle networks, making them suitable for use in composites, biomedicine, electronics, and many other fields. In this review, we present the latest advancements in the production of nanocellulose, including preparation technologies and methods for chemical and physical modifications to enhance the performance of these materials. We also discuss various applications, such as its use in nanocomposites, sustainable packaging materials, flexible electronic devices, and as a support for biological media. Additionally, the challenges and opportunities related to the scalability of production and their integration into industries with growing economic and ecological demands are explored. The review provides a comprehensive overview of the potential of nanocellulose, highlighting its importance in the context of emerging technologies and sustainability.
The evolution from conventional to modern agricultural practices, characterized by Agriculture 4.0 principles such as the application of innovative materials, smart water, and nutrition management, addresses the present-day challenges of food supply. In this context, polymer hydrogels have become a promising material for enhancing agricultural productivity due to their ability to retain and then release water, which can help alleviate the need for frequent irrigation in dryland environments. Furthermore, the controlled release of fertilizers by the hydrogels decreases chemical overdosing risks and the environmental impact associated with the use of agrochemicals. The potential of polymer hydrogels in sustainable agriculture and farming and their impact on soil quality is revealed by their ability to deliver nutritional and protective active ingredients. Thus, the impact of hydrogels on plant growth, development, and yield was discussed. The question of which hydrogels are more suitable for agriculture—natural or synthetic—is debatable, as both have their merits and drawbacks. An analysis of polymer hydrogel life cycles in terms of their initial material has shown the advantage of bio-based hydrogels, such as cellulose, lignin, starch, alginate, chitosan, and their derivatives and hybrids, aligning with sustainable practices and reducing dependence on non-renewable resources.
This paper provides a solid foundation for understanding the synthesis, properties, and applications of cellulose-based gels. It effectively showcases the potential of these gels in diverse applications, particularly in biomedicine, and highlights key synthesis methods and properties. However, to push the field forward, future research should address the gaps in understanding the environmental impact, mechanical stability, and scalability of cellulose-based gels, while also considering how to overcome barriers to their industrial use. This will ultimately allow for the realization of cellulose-based gels in large-scale, sustainable applications.
14 May 2019 in Journal of Analytical Methods in Chemistry
Measurement of antioxidant capacity represents an analytical major challenge in terms of accuracy, efficiency, rapid response, or low cost of detection methods. Quantification of antioxidant capacity of food samples using disposable screen‐printed microelectrodes (SPMEs) was based on cyclic voltammetry versus open-circuit potential (CV vs OCP) and differential pulse voltammetry (DPV) as compared with spectrophotometric measurement of the CUPRAC reaction with 6-hydroxy-2,5,7,8-tetramethylchroman-2-carboxylic acid (trolox). The SPMEs are organic‐resistant electrodes and thus compatible with food samples and organic solvents used to dissolve trolox. A micropipette was used to release a drop of 50 μL sample on the spotted surface of the SPME sensor/working electrode that was time programmed to function according to the working protocol. The SPME response was linearly correlated with trolox content. This preliminary demonstration was focused on the analysis of tea infusions, due to the simplicity and reproducibility of the samples’ preparations involved. Analytical results of the antioxidant capacity (expressed as mol·L−1 trolox equivalents) of the tea samples showed a good agreement in the case of spectrophotometry and differential pulse voltammetry (R2 > 0.998). DPV with SPME based on CUPRAC reactions was proven to be a promising approach for the characterization of antioxidant capacity of tea samples with rapid response, cost-effectiveness, and simplicity of operation.
In the present work, precipitated calcium carbonate (PCC) and carboxymethyl chitosan (CMC) were prepared to obtain new hybrid materials used in papermaking. In the first step, occurred the precipitation of CaCO3 in solution containing CMC at different levels (0.5%, 1%, and 1.5%). In the second step, PCC–CMC hybrid material (25%) was added to pulp suspension, and the sheets were made. The effect of PCC–CMC on paper properties (mechanical and optical) was systematically investigated. Breaking length, the brightness and opacity of the sheets obtained with the PCC–CMC material were better than the sheets fabricated with the unmodified PCC at similar levels of content.