Non-aqueous or gaseous stimulants are alternative working fluids to water for hydraulic fracturing in shale reservoirs, which offer advantages including conserving water, avoiding clay swelling and decreasing formation damage. Hence, it is crucial to understand fluid-driven fracture propagation and morphology in shale formations. In this research, we conduct fracturing experiments on shale samples with water, liquid carbon dioxide, and supercritical carbon dioxide to explore the effect of fluid characteristics and in situ stress on fracture propagation and morphology. Moreover, a numerical model that couples rock property heterogeneity, micro-scale damage and fluid flow was built to compare with experimental observations. Our results indicate that the competing roles between fluid viscosity and in situ stress determine fluid-driven fracture propagation and morphology during the fracturing process. From the macroscopic aspect, fluid-driven fractures propagate to the direction of maximum horizontal stress direction. From the microscopic aspect, low viscosity fluid easily penetrates into pore throats and creates branches and secondary fractures, which may deflect the main fracture and eventually form the fracture networks. Our results provide a new understanding of fluid-driven fracture propagation, which is beneficial to fracturing fluid selection and fracturing strategy optimization for shale gas hydraulic fracturing operations.

We report experimental observations of permeation of CO₂-rich aqueous fluids of varied acidic potential (pH) on three different shales to investigate mechanical, chemical, and mineralogical effects on fracture permeability evolution. Surface profilometry and SEM-EDS (scanning electron microscopy with energy-dispersive X-ray spectroscopy) methods are employed to quantify the evolution in both roughness on and chemical constituents within the fracture surface. Results indicate that, after 12 hours of fluid flow, fracture effective hydraulic apertures evolve distinctly under different combinations of shale mineralogy, effective stress, and fluid acidity. The evolution of roughness and transformation of chemical elements on the fracture surface are in accordance with the evolution of permeability. The experimental observations imply that (1) CO₂-rich aqueous fluids have significant impact on the evolution of fracture permeability and may influence (and increase) shale gas production; (2) shale mineralogy, especially calcite mineral, decides the chemical reaction and permeability increasing when CO₂-rich aqueous fluids flow through fractures by free-face dissolution effect; (3) clay mineral swelling reduces fracture aperture and additively calcite pressure solution removes the bridging asperities, which are the main reasons for fracture permeability decrease; (4) competition roles among clay mineral swelling, mineral pressure solution, and free-face dissolution determine how fracture permeability changes. Furthermore, a multiple parameter model is built to analyze effective hydraulic aperture evolution in considering above three mechanisms, which provide a reference to forecast fracture permeability evolution in shale formations.