Context. JWST has taken the sharpest and most sensitive infrared (IR) spectral imaging observations ever of the Orion Bar photodis-sociation region (PDR), which is part of the nearest massive star-forming region the Orion Nebula, and often considered to be the ‘prototypical’ strongly illuminated PDR. Aims. We investigate the impact of radiative feedback from massive stars on their natal cloud and focus on the transition from the H II region to the atomic PDR – crossing the ionisation front (IF) –, and the subsequent transition to the molecular PDR – crossing the dissociation front (DF). Given the prevalence of PDRs in the interstellar medium and their dominant contribution to IR radiation, understanding the response of the PDR gas to far-ultraviolet (FUV) photons and the associated physical and chemical processes is fundamental to our understanding of star and planet formation and for the interpretation of any unresolved PDR as seen by JWST. Methods. We used high-resolution near-IR integral field spectroscopic data from NIRSpec on JWST to observe the Orion Bar PDR as part of the PDRs4All JWST Early Release Science programme. We constructed a 3″ × 25″’ spatio-spectral mosaic covering 0.97– 5.27 μm at a spectral resolution R of ~2700 and an angular resolution of 0.075″–0.173″. To study the properties of key regions captured in this mosaic, we extracted five template spectra in apertures centred on the three H₂ dissociation fronts, the atomic PDR, and the H II region. This wealth of detailed spatial-spectral information was analysed in terms of variations in the physical conditions-incident UV field, density, and temperature – of the PDR gas. Results. The NIRSpec data reveal a forest of lines including, but not limited to, He I, H I , and C I recombination lines; ionic lines (e.g. Fe III and Fe II); O I and N I fluorescence lines; aromatic infrared bands (AIBs, including aromatic CH, aliphatic CH, and their CD counterparts); pure rotational and ro-vibrational lines from H₂; and ro-vibrational lines from HD, CO, and CH⁺, with most of them having been detected for the first time towards a PDR. Their spatial distribution resolves the H and He ionisation structure in the Huygens region, gives insight into the geometry of the Bar, and confirms the large-scale stratification of PDRs. In addition, we observed numerous smaller-scale structures whose typical size decreases with distance from θ¹ Ori C and IR lines from C I , if solely arising from radiative recombination and cascade, reveal very high gas temperatures (a few 1000 K) consistent with the hot irradiated surface of small-scale dense clumps inside the PDR. The morphology of the Bar, in particular that of the H₂ lines, reveals multiple prominent filaments that exhibit different characteristics. This leaves the impression of a ‘terraced’ transition from the predominantly atomic surface region to the CO-rich molecular zone deeper in. We attribute the different characteristics of the H₂ filaments to their varying depth into the PDR and, in some cases, not reaching the C⁺/C/CO transition. These observations thus reveal what local conditions are required to drive the physical and chemical processes needed to explain the different characteristics of the DFs and the photochemical evolution of the AIB carriers. Conclusions. This study showcases the discovery space created by JWST to further our understanding of the impact radiation from young stars has on their natal molecular cloud and proto-planetary disk, which touches on star and planet formation as well as galaxy evolution.

Massive stars disrupt their natal molecular cloud material through radiative and mechanical feedback processes. These processes have profound effects on the evolution of interstellar matter in our Galaxy and throughout the universe, from the era of vigorous star formation at redshifts of 1–3 to the present day. The dominant feedback processes can be probed by observations of the Photo-Dissociation Regions (PDRs) where the far-ultraviolet photons of massive stars create warm regions of gas and dust in the neutral atomic and molecular gas. PDR emission provides a unique tool to study in detail the physical and chemical processes that are relevant for most of the mass in inter- and circumstellar media including diffuse clouds, proto-planetary disks, and molecular cloud surfaces, globules, planetary nebulae, and star-forming regions. PDR emission dominates the infrared (IR) spectra of star-forming galaxies. Most of the Galactic and extragalactic observations obtained with the James Webb Space Telescope (JWST) will therefore arise in PDR emission. In this paper we present an Early Release Science program using the MIRI, NIRSpec, and NIRCam instruments dedicated to the observations of an emblematic and nearby PDR: the Orion Bar. These early JWST observations will provide template data sets designed to identify key PDR characteristics in JWST observations. These data will serve to benchmark PDR models and extend them into the JWST era. We also present the Science-Enabling products that we will provide to the community. These template data sets and Science-Enabling products will guide the preparation of future proposals on star-forming regions in our Galaxy and beyond and will facilitate data analysis and interpretation of forthcoming JWST observations.

We report cosmic ray ionization rates toward ten reddened stars studied within the framework of the EDIBLES (ESO Diffuse Interstellar Bands Large Exploration Survey) program, using the VLT-UVES. For each sightline, between two and ten individual rotational lines of OH ⁺ have been detected in its (0,0) and (1,0) A ³ Π − X ³ Σ ⁻ electronic band system. This allows constraining of OH ⁺ column densities toward different objects. Results are also presented for 28 additional sightlines for which only one or rather weak signals are found. An analysis of these data makes it possible to derive the primary cosmic ray ionization rate ζ _p in the targeted diffuse interstellar clouds. For the ten selected targets, we obtain a range of values for ζ _p equal to (3.9 – 16.4) × 10 ⁻¹⁶ s ⁻¹ . These values are higher than the numbers derived in previous detections of interstellar OH ⁺ in the far-infrared/submillimeter-wave regions and in other near-ultraviolet studies. This difference is a result of using new OH ⁺ oscillator strength values and a more complete picture of all relevant OH ⁺ formation and destruction routes (including the effect of proton recombinations on PAHs), and the relatively high N (OH ⁺ ) seen toward those ten targets.

Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): (ionized Buckminsterfullerene). Confirming the presence of this molecule would have significant implications regarding the carbon budget and chemical complexity of the ISM. Here we present results from a new method for ultra-high signal-to-noise ratio (S/N) spectroscopy of background stars in the near-infrared (at wavelengths of 0.9–1 μm), using the Hubble Space Telescope (HST) Imaging Spectrograph (STIS) in a previously untested “STIS scan” mode. The use of HST provides the crucial benefit of eliminating the need for error-prone telluric-correction methods in the part of the spectrum where the bands lie and where the terrestrial water vapor contamination is severe. Our STIS spectrum of the heavily reddened B0 supergiant star BD+63 1964 reaches an unprecedented S/N for this instrument (∼600–800), allowing the detection of the diffuse interstellar band (DIB) at 9577 Å attributed to , as well as new DIBs in the near-IR. Unfortunately, the presence of overlapping stellar lines, and the unexpected weakness of the bands in this sightline, prevents conclusive detection of the weaker bands. A probable correlation between the 9577 Å DIB strength and interstellar radiation field is identified, which suggests that more strongly irradiated interstellar sightlines will provide the optimal targets for future searches.

Context. An unambiguous identification of the carriers of the diffuse interstellar bands (DIBs) would provide important clues to the life cycle of interstellar matter. The so-called C₂-DIBs are a class of very weak bands that fall in the blue part of the optical spectrum and are associated with high column densities of the C₂ molecule. DIB profile structures constrain potential molecular carriers, but their measurement requires high signal-to-noise, high-resolution spectra and the use of sightlines without Doppler splitting, as typical for a single-cloud situation. Aims. Spectra from the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) conducted at the Very Large Telescope (ESO/Paranal) were explored to identify single-cloud and high C₂ column sightlines, extract the corresponding C₂-DIBs and study their strengths and profiles, and to investigate in detail any sub-structures. Methods. The target selection was made based on profile-fitting of the 3303 and 5895 Å Na I doublets and the detection of C₂ lines. The C₂ (2–0) (8750–8849 Å) Phillips system was fitted using a physical model of the host cloud. C₂ column densities, temperatures as well as gas densities were derived for each sightline. Results. Eighteen known C₂-DIBs and eight strong non-C₂ DIBs were extracted towards eight targets, comprising seven single-cloud and one multi-cloud line-of-sights. Correlational studies revealed a tight association of the former group with the C₂ columns, whereas the non-C₂ DIBs are primarily correlated with reddening. We report three new weak diffuse band candidates at 4737.5, 5547.4, and 5769.8 Å. We show for the first time that at least 14 C₂-DIBs exhibit spectral sub-structures which are consistent with unresolved rotational branches of molecular carriers. The variability of their peak separations among the bands for a given sightline implies that their carriers are different molecules with quite different sizes. We also illustrate how profiles of the same DIB vary among targets and as a function of physical parameters, and provide tables defining the sub-structures to be compared with future models and experimental results.

Context.Mid-infrared emission features are important probes of the properties of ionized gas and hot or warm molecular gas, which are difficult to probe at other wavelengths. The Orion Bar photodissociation region (PDR) is a bright, nearby, and frequently studied target containing large amounts of gas under these conditions. Under the “PDRs4All” Early Release Science Program for JWST, a part of the Orion Bar was observed with MIRI integral field unit (IFU) spectroscopy, and these high-sensitivity IR spectroscopic images of very high angular resolution (0.2″) provide a rich observational inventory of the mid-infrared (MIR) emission lines, while resolving the HIIregion, the ionization front, and multiple dissociation fronts.Aims.We list, identify, and measure the most prominent gas emission lines in the Orion Bar using the new MIRI IFU data. An initial analysis summarizes the physical conditions of the gas and demonstrates the potential of these new data and future IFU observations with JWST.Methods.The MIRI IFU mosaic spatially resolves the substructure of the PDR, its footprint cutting perpendicularly across the ionization front and three dissociation fronts. We performed an up-to-date data reduction, and extracted five spectra that represent the ionized, atomic, and molecular gas layers. We identified the observed lines through a comparison with theoretical line lists derived from atomic data and simulated PDR models. The identified species and transitions are summarized in the main table of this work, with measurements of the line intensities and central wavelengths.Results.We identified around 100 lines and report an additional 18 lines that remain unidentified. The majority consists of HIrecombination lines arising from the ionized gas layer bordering the PDR. The HIline ratios are well matched by emissivity coefficients from H recombination theory, but deviate by up to 10% because of contamination by HeIlines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni. We show how the NeIII/NeII, SIV/SIII, and ArIII/ArIIratios trace the conditions in the ionized layer bordering the PDR, while FeIII/FeIIand NiIII/NiIIexhibit a different behavior, as there are significant contributions to FeIIand NiIIfrom the neutral PDR gas. We observe the pure-rotational H₂lines in the vibrational ground state from 0–0S(1) to 0–0S(8), and in the first vibrationally excited state from 1–1S(5) to 1–1 S(9). We derive H₂excitation diagrams, and for the three observed dissociation fronts, the rotational excitation can be approximated with one thermal (~700 K) component representative of an average gas temperature, and one nonthermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model of the Orion Bar PDR, and find that the predicted excitation matches the data qualitatively, while adjustments to the parameters of the PDR model are required to reproduce the intensity of the 0–0 S (6) to S (8) lines.