Magnetic skyrmions are topological quasiparticles in magnetization. Recently, as one of their photonic counterparts, Néel-type photonic skyrmions were discovered in evanescent electromagnetic waves. The deep-subwavelength features of the photonic skyrmions suggest their potential in optical imaging quantum technologies and data storage. Here, by exploiting the photonic quantum spin Hall effect of a plasmonic vortex in a trilayered structure, we predict the existence of photonic twisted-Néel- and Bloch-type skyrmions in chiral materials. Their chirality-dependent features can be considered as additional degrees of freedom for future chiral sensing, information processing, and storage technologies. In particular, our findings enrich the formations of photonic skyrmions and reveal a remarkable resemblance of the feature of chiral materials in two seemingly distant fields: photonic skyrmions and magnetic skyrmions.

Optical skyrmions, quasiparticles that are characterized by the topologically nontrivial vectorial textures of optical parameters such as the electromagnetic field, Stokes parameters, and spin angular momentum, have aroused great attention recently. New dimensions for optical information processing, transfer, and storage have become possible, and developing multiple schemes for manipulating the topological states of skyrmions, thus, is urgent. Here we propose an approach toward achieving dynamic modulation of skyrmions via changing the field symmetry and adding chirality. We demonstrate that field symmetry governs the skyrmionic transformation between skyrmions and merons, whereas material chirality modulates the twist degree of fields and spins and takes control of the Néel-type–Bloch-type skyrmionic transition. Remarkably, the enantioselective twist of skyrmions and merons results from the longitudinal spin arising from the chirality-induced splitting of the hyperboloid in the momentum space. Our investigation, therefore, acts to enrich the portfolio of optical quasiparticles. The chiral route to topological state transitions will deepen our understanding of light–matter interaction and pave the way for chiral sensing, optical tweezers, and topological phase transitions in quantum matter.

The discrimination and separation of chiral enantiomers can be realized due to the quantum spin Hall effect of surface-plasmon-polaritons.

Intrinsic spin-momentum locking is an inherent property of surface electromagnetic fields and its study has led to the discovery of phenomena such as unidirectional guided waves and photonic spin lattices. Previously, dispersion was ignored in spin-momentum locking, resulting in anomalies contradicting the apparent physical reality. Here, we formulate four dispersive spin-momentum equations, revealing in theory that transverse spin is locked with kinetic momentum. Moreover, in dispersive metal or magnetic materials spin-momentum locking obeys the left-hand screw rule. In addition to dispersion, structural features can affect substantially this locking. Remarkably, an extraordinary spin originating from coupling polarization ellipticities is uncovered that depends on the symmetry of the field modes. We further identify the properties of this spin-momentum locking with diverse photonic topological lattices by engineering their rotational symmetry akin to that in solid-state physics. The concept of spin-momentum locking based on photon flow properties translates easily to other classical wave fields.

One of the most fascinating properties of chiral molecules is their ability to rotate the polarization of light. Since Faraday's experiments in 1845, it has been known that nonreciprocal polarization rotatory power can be induced by a magnetic field. But can reciprocal polarization rotation in chiral molecules be influenced by an electric field? In the 1960s, Aizu and Zheludev introduced the phenomenon of electrogyration. While the linear (Pockels) and quadratic (Kerr) electro‐optical effects describe how an external electric field changes linear birefringence and dichroism, electrogyration describes how a field changes the circular birefringence and dichroism of a medium. Electrogyration is observed in dielectrics, semiconductors, and ferroelectrics, but the effect is small. This work demonstrates a nanostructured photonic metamaterial that exhibits quadratic electrogyration—proportional to the square of the applied electric field—six orders of magnitude stronger than in any natural medium. Giant quadratic electrogyration emerges as electrostatic forces acting against forces of elasticity change the chiral configuration of the metamaterial's nanoscale building blocks and consequently its polarization rotatory power. This observation of giant electrogyration alters the perception of the effect from that of an esoteric phenomenon into a functional part of the electro‐optic toolkit with application potential.