In the past two decades, we have learned a great deal about self-assembly of dendritic metal oxide structures, partially inspired by the nanostructures mimicking the aesthetic hierarchical structures of ferns and corals. The self-assembly process involves either anisotropic polycondensation or molecular recognition mechanisms. The major driving force for research in this field is due to the wide variety of applications in addition to the unique structures and properties of these dendritic nanostructures. Our purpose of this minireview is twofold: (1) to showcase what we have learned so far about how the self-assembly process occurs; and (2) to encourage people to use this type of material for drug delivery, renewable energy conversion and storage, biomaterials, and electronic noses.
Dye-sensitized solar cells (DSSCs) are regarded as one of the most promising solar cells amongst third-generation photovoltaic technologies, particularly due to their low cost, easy preparation, and minor environmental impact compared to earlier-generation devices. However, they have been challenged by thermal energy losses and low cell efficiencies. This work examined the incorporation of zirconium (Zr) into the crystal lattice of titania nanoparticles (nTiO2) for subsequent fabrication into the photo anode of the DSSCs. The results showed that Zr doping of nTiO2 inhibited the anatase-rutile phase transition. Higher calcination temperatures gave increased titania crystallinity, and stabilized the nTiO2 aggregate pore structure and specific surface area, consequently improving the DSSC device performance. A doping concentration of 5 mol % Zr into the nTiO2 demonstrated the best resistance against thermal degradation, achieving an optimized retention of specific surface area. Solar simulation confirmed the results, indicating better heat stability, although lowering the DSSC efficiencies.
15 August 2022 in The Journal of Supercritical Fluids
This review provides a comprehensive overview of dental materials that promote tissue healing while exhibiting antimicrobial properties. The focus is on materials that are biocompatible, bioactive, and non-toxic to host cells, with demonstrated bacteriostatic and bactericidal activities. Current advances in natural bactericides, antimicrobial polymers, and bioactive glass/polymer composites are summarized, along with techniques employed for surface modification and the coating of dental implants. Three major categories of antimicrobial coatings were identified: antibacterial phytochemicals, synthetic antimicrobial agents (including polymers and antibiotics), and metallic nanoparticles. Bioactive coatings were further examined to identify potential antimicrobial strategies within these materials, and existing research gaps were highlighted. A systematic literature search was conducted in PubMed, Scopus, and Web of Science for articles published between January 2010 and June 2025. Overall, this review underscores the growing potential of multifunctional dental materials that integrate bioactivity with antimicrobial performance, offering promising directions for the development of next-generation restorative and implant materials.