As a new type of energy that can meet the requirements of carbon neutrality, biomass has received wide attention in recent years, and its rational and efficient thermal utilization can help reduce greenhouse gas emissions and establish an energy-saving, low-carbon energy system to promote sustainable development. In this paper, the current utilization and research status of plant-based biomass waste is comprehensively summarized from four aspects, namely component properties, industrial thermal utilization means, experiments and theoretical calculations. In addition, this paper summarizes the research progress in several aspects, such as microscopic experimental studies, macroscopic pyrolysis characterization, and multiscale theoretical model construction of biomass waste. However, due to the diversity and heterogeneity of biomass, there are still some challenges to extending the laboratory research results to large-scale industrial production, for which we also provide an outlook on future technological innovations and development directions in this research area.

Hydrogen production from ethanol steam reforming (ESR) was performed using the synthesized LaNi_xCu_1−xO_3−λ perovskite-type catalysts in a continuous two-stage fixed-bed reactor from 450 to 700 °C under atmospheric pressure. The elemental analysis (EA), XRD, SEM, BET, and TGA-DTG technologies were used to characterize the structures and properties of the synthesized catalysts. The thermodynamic equilibrium model, based on the minimization of Gibbs free energy using a non-stoichiometric methodology, was carried out and compared with experimental data. The results demonstrated that the catalytic activity of the perovskite-type catalysts for ESR can be improved after modification with a certain amount of copper (about 0.67 mmol/g) and decreased further with an increase in copper content (about 3.41 mmol/g). The most active catalyst was found to be LaNi_0.9Cu_0.1O_3−λ, with an ethanol conversion value of 96.0% and hydrogen selectivity of 71.3%. The perovskite-type catalysts with an appropriate amount of Cu promoter improved coking resistance and presented excellent stability with no loss of activity over 101 h at 700 °C. Based on the power-law kinetic model with the first reaction order, the activation energy and the frequency factor for ethanol steam reforming by perovskite-type catalysts were calculated. Our studies indicated the enhanced effects of Ni and Cu on the small Ni-Cu bimetallic particles in the water gas shift (WGS) reaction, which could also contribute to the activity and stability of the LaNi_xCu_1−xO_3−λ perovskite-type catalysts in hydrogen production.