The alluvial plain (Anqing section) of the lower reaches of the Yangtze River basin is facing increasing groundwater pollution, not only threatening the safety of drinking water for local residents and the sustainable development and utilization of groundwater resources but also the ecological security of the Yangtze River Basin. Therefore, it is necessary to conduct a preliminary analysis on the hydrochemical characteristics and evolution law of groundwater in this area. This study aimed to evaluate potential hydrogeochemical processes affecting the groundwater quality of this area by analyzing major ions in groundwater samples collected in 2019. Compositional relationships were determined to assess the origin of solutes and confirm the predominant hydrogeochemical processes controlling various ions in groundwater. Moreover, factors influencing groundwater quality were evaluated through the factor analysis method, and the control range of each influencing factor was analyzed using the distribution characteristics of factor scores. Finally, reverse hydrogeochemical simulation was carried out on typical profiles to quantitatively analyze the hydrochemical evolution process along flow paths. The Piper trilinear diagram revealed two prevalent hydrochemical facies, Ca-HCO3 type (phreatic water) and Ca-Na-HCO3 type (confined water) water. Based on the compositional relationships, the ions could be attributed to leaching (dissolution of rock salt, carbonate, and sulfate), evaporation and condensation, and cation exchange. Four influencing factors of phreatic water and confined water were extracted. The results of this study are expected to help understand the hydrochemical characteristics and evolution law of groundwater in the alluvial plain (Anqing section) of the lower Yangtze River basin for effective management and utilization of groundwater resources, and provide basic support for the ecological restoration of the Yangtze River Basin.
Some provinces in China require zero discharge of coal mine wastewater, with a focus on the disposal of high-salt water, because evaporation ponds have been completely banned. Deep geological storage (DGS) technology is a novel geological environment solution that uses rock pores and microfissures within deep strata for safely storing liquid or gas to avoid its environmental impact on the biosphere. The author and his research team were the first to put forward the research idea of using DGS technology to dispose of high-salinity brine in coal mines in China and performed related research. Taking a coal mine in the south of Ordos Basin as an example, this study designed a conventional, mine-specific, zero-discharge water treatment process route based on a evaporation–crystallization process. This strategy was tailored to the unique water inflow conditions of the mine. Furthermore, the technical and economic efficiencies were assessed for the generation and treatment scenarios of a four-stage highly concentrated brine solution. In addition, the comparative analysis of the economic prospects of using DGS technology to treat high-salinity brine revealed that combining DGS with post-conventional treatment in secondary reverse osmosis, whose flow quality is 481 m3/h and TDS is 24,532.66 mg/L, can maximize the economic benefits. This integration heightened water resource utilization while maintaining a cost-effective, comprehensive water treatment approach. These results provide a valuable reference value for the future zero-discharge treatment of coal mine water.
Deep well injection and storage (DWIS) has recently been proposed and implemented to achieve zero mine water emissions. In 2023, DWIS for highly saline mine water was successfully applied to a local mine in the Ordos Basin for the first time with excellent performance. However, the storage characteristics of highly saline mine water in the storage layer during DWIS remain unclear. This study was conducted in situ with real-time, online monitoring of instantaneous flow and injection pressure, along with synchronous micro-seismic monitoring during the early stages of DWIS, based on the geological conditions and spatial structure of the storage layer. The results indicated that the early seepage characteristics of the fluid geological storage did not conform to Darcy’s law. Within a certain pressure range, as the water pressure increased, the flow also increased. However, beyond this range, further increases in pressure caused a gradual decline in the flow. During the initial phase of storage, the migration of high-salinity mine water within the storage layer occurred in two stages: breakthrough and stabilization. During the breakthrough stage, the water injection pressure propagated to the flooding front, overcoming the formation stress and expanding the storage space. At this stage, mine water primarily filled the pore microcracks within the flooding front. In the initial 10 days of storage, high-salinity mine water in the study area affected approximately 42,104 m2 of the storage layer plane. The injection well affected an area nearly 200 m in depth, extending approximately 190 m northward and approximately 40 m upward. The predominant diffusion directions were northeast and east–southeast from the injection well. These findings could provide valuable insights into the treatment of highly saline mine water in the Ordos Basin, demonstrate the feasibility and safety of DWIS, and offer significant scientific contributions to the prevention and control of mine water pollution.
Deep well injection and storage is an emerging technology for realizing the low-cost treatment of extremely large quantities of three types of waste in coal mines in China, while simultaneously supporting coordinated development that considers its impact on the ecological environment. There has been significant progress in research on the geological storage of carbon dioxide in China. However, the geological storage of fluids such as mine water and high-salinity water needs to be studied further. Based on a comprehensive analysis of the lithology, mineral composition, physical and mechanical characteristics, and spatial structure of the Liujiagou and Shiqianfeng formations in a mining area in the Ordos Basin, we determined the geological storage space for fluids, predicted the storage potential, and evaluated the feasibility of deep geological storage of high-salinity water in coal mines. In the study area, the Liujiagou Formation is dominated by fine sandstone and siltstone, while the Shiqianfeng Formation is dominated by medium sandstone and conglomerate. The main storage space comprises micro-cracks, as well as intergranular, dissolution, and intergranular pores. Among these, the intergranular pores are the most conducive to reservoir development. The burial depth intervals of 1820–1835 m, 1905–1920 m, and 2082–2098 m are favorable for storage and are characterized by high porosities, permeabilities, and storage capacities. The effective storage capacity within a 100 m radius of the storage well was estimated to be 33.15 × 104 m3. The effective storage capacity in the favorable area is 27.69 × 104 m3, accounting for 83.50% of the total storage capacity. The Liujiagou and Shiqianfeng formations thus can serve as favorable reservoirs for deep well injection and storage of high-salinity water in the Ordos Basin. This research provides new ideas for the treatment of high-salinity water in coal mines in the Ordos Basin and technical support for deep well injection and the storage of high-salinity water.
Riverbank filtration (RBF) is increasingly being used as a relatively cheap and sustainable means to improve the quality of surface water. Due to the obvious differences in physical, chemical, and biological characteristics between river water and groundwater, there are strong and complex physical, chemical, and biogeochemical effects in the process of bank filtration. In this paper, multivariate statistical analysis was used to identify the spatial variation of hydrogeochemical groundwater in the process of bank filtration. Firstly, the evolution process of groundwater hydrochemistry during the filtration process was identified through factor analysis. According to the results, the evolution of groundwater hydrochemistry in this area is attributable to four main types of reactions: (1) Leaching; (2) Regional groundwater influence; (3) Aerobic respiration and denitrification; and (4) Mn (IV)/Fe (III)/SO42− reduction. According to the similarity of the geochemistry, the flow path could be divided into four different hydrochemical zones through cluster analysis, revealing the evolution law of groundwater hydrochemistry and its main influencing factors during riverbank infiltration. Large hydraulic gradient in The Zone Strongly Influenced by River Water (The first group) resulted in a weak effect of leaching on groundwater chemistry. Reoxygenation and microorganism respiration occurred in The Zone Moderately Influenced by River Water (The second group), The Zone Weakly Influenced by River Water (The third group), and The Zone Strongly Influenced by Regional Groundwater (The fourth group), resulting in fluctuations in Eh and pH values of groundwater. As a result, sulfate reduction and Mn (IV) and Fe (III) reduction alternated along the flow path. The Zone Strongly Influenced by Regional Groundwater (The fourth group) groundwater chemistry was mainly affected by regional groundwater.
Deep well injection and storage (DWIS) technology provides an effective alternative to address the high cost, energy intensity, and limited scalability of conventional treatments for high-salinity mine water from coal mines. However, the absence of a dedicated site suitability evaluation framework remains a major gap. Unlike previous approaches that directly applied CO2 storage criteria, this study refines and restructures the framework based on a systematic analysis of the fundamental differences in mechanisms and risk characteristics unique to mine water storage. Building on the experience of CO2 geological storage assessment, this study analyzes the key differences in fluid properties and storage mechanisms between water and CO2 and, for the first time, establishes a comprehensive site suitability evaluation framework for mine water geological storage. The framework integrates three main dimensions—stability and safety, effectiveness, and socio-economic factors—covering 80 key parameters. The indicator system is organized hierarchically at the basin, target-area, and site levels, and incorporates a multi-scale weight adaptation mechanism that assigns scale-dependent weights to the most influential indicators at each evaluation level. An innovative evaluation methodology combining a “one-vote veto” mechanism, progressive filtering, and multi-factor weighted superposition is proposed to determine storage suitability. This work fills a critical research gap in systematic site selection for deep mine water storage in China. It offers theoretical guidance and an engineering paradigm for overcoming technological bottlenecks in high-salinity water treatment, enabling efficient and low-carbon disposal. The study has important implications for promoting the green transformation of the mining industry and achieving national carbon peaking and neutrality goals.