In this study, plasma nitriding and multi-arc ion plating techniques were employed to enhance the load-bearing capacity of the TC4 alloy. The tribological properties were characterized, and the mechanisms were discussed in detail. Subsequently, the tribological properties of the coating enhanced with MoS2 were then evaluated, and the results indicated that the plasma nitriding treatment, which exhibited optimal friction performance, resulted in the formation of a nitrided layer with a thickness of 98 μm on the surface of the TC4 alloy, thereby significantly improving its mechanical properties. Furthermore, the TiN coating samples treated with plasma nitriding demonstrated superior mechanical properties, achieving the highest hardness value (20 GPa), high load-carrying capacity (58 N) and the lowest wear rate (9.16 × 10−6 mm3·N−1·m−1). Moreover, the tribological properties of MoS2 deposited on the surface of the PN-2/TiN sample were significantly enhanced, which can be attributed to the synergistic effect of the excellent load-bearing characteristics of the plasma nitriding treatment and the wear resistance of the TiN layer. This study investigates the factors contributing to the superior tribological performance of the PN-2/TiN sample and the extended friction lifetime of the PN-2/TiN/MoS2 sample. The composite coating provides a new method to improve the anti-friction of soft metals, especially titanium alloys, and is expected to be applied in the aerospace field.
To improve the friction performance and service life of protective coatings in humidity-fluctuating environments, porous hard titanium nitride (TiN)–molybdenum disulfide (MoS2) composite coatings were prepared by using direct current magnetron sputtering (DCMS) with the mode of oblique angle deposition (OAD) and chemical vapor deposition (CVD) technologies. The structure and chemical component were characterized by field emission scanning electron microscopy (FESEM), energy dispersive spectrometer (EDS), grazing incidence X-ray diffraction (GIXRD), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. The tribological properties of these TiN–MoS2 composite coatings were investigated. The results indicate that the porous TiN–MoS2 composite coating exhibited outstanding friction performance and long service life under humidity-fluctuating environments. At the initial 20% relative humidity (RH) stage, the MoS2 on the porous TiN–MoS2 composite coating surface worked as an effective lubricant; thus, the coating demonstrated excellent lubrication performance, and the friction coefficient (COF) was about 0.05. As the humidity was alternated to 70% RH, the lubrication effect diminished due to the production of molybdenum oxide (MoO3), and the COF was about 0.2, which was attributed to the degradation of MoS2 on the wear track and the release of fresh MoS2 from the porous TiN matrix. After the environmental conditions shifted from 70% to 20% RH, the MoO3 was removed, and the lubrication effect was restored. In summary, TiN–MoS2 porous composite coating offers a promising approach for lubrication in humidity-fluctuating environments.
5 December 2022 in Plasma Physics and Controlled Fusion
The nonlinear evolution of the tearing mode instability with toroidal rotation is investigated using a three-dimensional toroidal geometry magnetohydrodynamic code (M3D). It is found that toroidal rotation plays a significantly stable role in reducing the width of magnetic island, which is independent of the direction of toroidal rotation. Compared with the stabilizing effect in the linear phase, the stabilizing effect of toroidal rotation is much stronger in the nonlinear phase. The magnetic island is almost suppressed by large enough rotation, even though the linear growth rate is weakly reduced in the linear phase. It is observed that the flow shear has a stabilizing effect, which is significant when the rotation frequency is large. However, it is shown that the magnitude of rotation plays a dominant role in stabilizing the magnetic island when the rotation frequency is small. The Coriolis force, rather than the centrifugal force, is found to play a dominant role in stabilizing the tearing mode in the nonlinear phase. When and tearing modes exist simultaneously, the sheared toroidal rotation is shown to effectively suppress the overlap of magnetic islands and field stochasticity caused by the coupling of neighboring islands.