The ampholytic chitosan based flocculant carboxylated chitosan graft-(3-chloro-2-hydroxypropyl) trimethylammonium chloride-dimethyl diallyl ammonium chloride (CPCTS-g-P (CTA-DMDAAC)) was synthesized by photo polymerization using carboxylated chitosan (CPCTS), 3-chloro-2-chloropropyltrimethylammonium chloride (CTA) and dimethyldiallylammonium chloride (DMDAAC) as the cationic co-monomers. The effects of monomer concentration, the ratio of CPCTS and cationic monomers, cationic degree, initiator time, photoinitiator concentration, and pH value on the properties of CPCTS-g-P (CTA-DMDAAC) were studied. The microcystis aeruginosa that was cultured in laboratory was used for CPCTS-g-P (CTA-DMDAAC) flocculation tests. The effects of CPCTS-g-P (CTA-DMDAAC) dosage, pH value and G value on flocculation performance were investigated. The maximum removal rate of chlorophyll-a (Chl-a) and chemical oxygen demand (COD) that were obtained by CPCTS-g-P (CTA-DMDAAC) were 98.8% and 96.5% under the conditions of dosage 4 mg/L, pH 7 and G value 200 s⁻¹, respectively. The flocculation experiments showed that chitosan-based flocculant CPCTS-g-P (CTA-DMDAAC) had better flocculation performance than commercially available flocculants cationic polyacrylamide (CPAM), Polyferric Sulfate (PFS), and polymeric aluminium (PAC).

To explore the migration differences of sediments at the front, middle, and end sections of a storm sewer when scoured by water, and further evaluate the pollution load, the scouring process of sediments at different locations of a storm sewer was simulated and mathematical models were built to calculate the scouring rate. Results show that scouring rate is affected by sediment particle size, pipeline slope, sediment thickness, and water flow velocity. As the slope increased, scouring rate at the end section increased more obviously. The scouring rate at the front section slightly decreased with increasing sediment thickness, but opposite trends were observed at the middle and end sections. When the particle size (0.33 mm–0.83 mm) and flow velocity (0.15 m/s–0.65 m/s) increased within their ranges, scouring rate increased across all three locations. Models for calculating scouring rate were established via two data fitting. The calculated values were compared with measured values at a scouring time of 1 min. Under different particle sizes, the difference between the calculated and measured values at front, middle, and end sections were in the ranges of −0.63% to 0.63%, −0.01% to 0.02%, and −0.13% to 0.16%, respectively, all of which showed good consistency.