The aggregation and the rapid restructuring of the photoinduced electron−hole pairs restructuring in the process of photoelectric response remains a great challenge. In this study, a kind of Multi-walled carbon nanotubes loaded Alpha-Fe2O3 (CNTs/α-Fe2O3) heterostructure composite is successfully prepared via the one-step method. Due to the synergistic effect in the as-prepared CNTs/α-Fe2O3, the defect sites and oxygen-containing functional groups of CNTs can dramatically improve the interface charge separation efficiency and prevent the aggregation of α-Fe2O3. The improved photocurrent and enhanced hole–electron separation rate in the CNTs/α-Fe2O3 is obtained, and the narrower band gap is measured to be 2.8 ev with intensive visible-light absorption performance. Thus, the CNTs/α-Fe2O3 composite serves as an excellent visible light photocatalyst and exhibits an outstanding photocatalytic activity for the cationic dye degradation of rhodamine B (RhB). This research supplies a fresh application area forα-Fe2O3 photocatalyst and initiates a new approach for design of high efficiency photocatalytic materials.
Most of existing piezoelectric polymers have low glass transition temperatures, so they can only operate at lower temperatures (500 ℃). Its output performance is improved with the increase of heat treatment temperature (<260 ℃) and then basically remains unchanged in a temperature range of 260–450 ℃. Finally, the output performance decreases at temperatures higher than 450 ℃. When the heat treatment temperature reaches 260 ℃, the output voltage increases to 10.08 V, and current reaches 2.89 μA. Compared with those of the untreated PAN membranes , its output voltage and current are increase by 3.54 times and 2.83 times, respectively. At the same time, the output of the PAN high temperature resistant flexible nanofiber film sensors is almost unchanged in the high-temperature environments. This is the first time that the pyroelectric effect has been observed in heat-treated PAN nanofiber films and both the open-circuit voltage and short-circuit current have been shown to increase with temperature gradient increasing. Besides, the PAN nanofiber film sensors have durability of more than 5000 cycles at room temperature(25 ℃) even at high temperature (400 ℃). Overall, good flexible, high-temperature resistance, and bifunctional sensing ability make PAN flexible nanofiber film sensors expected to be widely used in high temperature environments such as fire safety, aerospace and other harsh environment.