To enhance the improvement effect of Enzyme-Induced Carbonate Precipitation (EICP) technology more effectively, an abundant renewable resource—lignin—was introduced as an additive during the EICP modification process of silty clay. The mechanical properties of the improved soil specimens were analyzed from a macroscopic point of view by using unconsolidated undrained (UU) triaxial tests and unconfined compressive strength (UCS) tests to determine the optimal lignin content and curing time. The micro-mechanism of the improved soil specimens was elucidated from the microscopic point of view by combining scanning electron microscopy (SEM) and X-ray diffraction (XRD) tests. The experimental results showed that lignin synergized with EICP could effectively improve the mechanical properties of the soil, and the mechanical properties of the co-consolidated soil specimens were better than those of the single consolidated and untreated soil specimens as a whole. The single EICP-consolidated soil specimen had undergone brittle damage; lignin could enhance the toughness of the soil and weaken its brittle characteristics. With the increase of lignin content, the mechanical indicators of co-consolidated soil specimens showed the trend of increasing and then decreasing, and reached the optimum at 0.75%. Moreover, the addition of lignin significantly increased the cohesive force, while the friction angle was less affected. With extended curing time, the mechanical indicators of the co-consolidated soil specimens increased overall, and tended to stabilize after 7 days of curing, hence selecting 7 days as the optimal curing time. From the microscopic point of view, lignin provides nucleation sites for the calcium carbonate precipitates generated by EICP, and the joint action of the two can fill the soil pores and cement the soil particles, thereby improving the overall strength of the soil. The results of the study can provide a theoretical basis and practical reference for the construction of foundation projects in silty clay areas.

The objective of this study was to enhance the mechanical properties of gravelly soil and to consider the binding and filling effects of xanthan gum and calcium lignosulfonate. To this end, gravelly soil samples were prepared with various dosages of xanthan gum and calcium lignosulfonate, and their curing effects were investigated. The mechanical properties and strength parameters of the cured gravelly soil were investigated using unconfined compressive strength (UCS) tests and conventional triaxial compression tests. Furthermore, scanning electron microscopy (SEM) was employed to examine the microstructure and curing mechanisms of the gravelly soil treated with these additives. The findings demonstrate that as the dosage increases, both xanthan gum and calcium lignosulfonate markedly enhance the compressive strength and shear strength of the gravelly soil. The curing effect of xanthan gum was found to be more pronounced with higher dosages, while the optimal curing effect for calcium lignosulfonate was achieved at a dosage of 4%. The gravelly soil treated with xanthan gum exhibited superior performance compared to that treated with calcium lignosulfonate when the same dosage was used. Moreover, at elevated confining pressures, the binding effect of xanthan gum and calcium lignosulfonate on the gravelly soil was less pronounced than the strength effect imparted by the confining pressure. This suggests that the impact of dosage on the shear strength of the gravelly soil is diminished at higher confining pressures. The stabilization of crushed stone soil by xanthan gum is a complex process that involves two main mechanisms: bonding and cementation, and filling and film-forming. The curing mechanism of calcium lignosulfonate-cured gravelly soil can be summarized as follows: ion exchange, adsorption and encapsulation, and pore filling and binding effects. The findings of this research offer significant insights that are pertinent to the construction of high earth–rock dams and related engineering applications.

Gravelly soils, characterized by a distinctive combination of coarse gravel aggregates and fine soil matrix, are widely distributed and play a crucial role in geotechnical engineering. This study investigates the mechanical behavior of gravelly soil subjected to simulated freeze-thaw (F-T) cycles using triaxial compressive strength tests. The long-term deviatoric stress response of specimens with varying gravel content and initial water content was analyzed under three distinct effective confining pressures (100, 200, and 300 kPa) across different F-T cycles. The results indicate that compressive strength is significantly influenced by gravel content, initial water content, and confining pressure. Notably, the rate of increase in deviatoric stress does not exhibit a proportional rise under confining pressures of 200 kPa and 300 kPa after 40 F-T cycles. However, a direct correlation is observed between deviatoric stress and increasing confining pressure (100, 200, and 300 kPa) over 2-, 4-, and 6-day intervals, this effect is more pronounced at higher confining pressures. The deviatoric stress peaks at different strain thresholds depending on the applied confining pressure; furthermore, no evident strain-softening behavior is observed across the tested conditions. These findings suggests that higher confining pressure inhibits particle displacement and interlocking failure, thereby reducing both the void ratio and axial strain within the soil matrix. Overall, these insights enhance our understanding of the complex interactions among gravel content, water content, confining pressure, and freeze-thaw effects, contributing to the understanding of the compressive strength evolution in gravelly soils under cyclic environmental loading.

This study presents an environmentally friendly alternative to conventional energy-intensive methods for soil improvement by investigating an enzyme-induced active magnesium oxide carbonation (EIMC) technique for the stabilization of gravelly soil. The solidification efficacy and strengthening mechanism of EIMC-treated soil were systematically investigated through a combination of mechanical property tests and microstructural analyses. Results indicate that key mechanical properties—including compressive strength, shear strength, and elastic modulus—were directly proportional to the magnesium oxide (MgO) content. Notably, an 8% MgO content resulted in a 113-fold increase in unconfined compressive strength (UCS) compared to the untreated soil. The strength development stabilized after a five-day curing period. While higher MgO content yielded greater absolute strength, the efficiency of strength gain per unit of MgO peaked at a 4% dosage. Consequently, considering both performance and efficiency, an MgO content of 4% and a curing period of 5 days are recommended as the optimal parameters. The EIMC treatment substantially improved the soil’s mechanical properties, inducing a transition in the failure mode from plastic to brittle, with this brittleness becoming more pronounced at higher MgO concentrations. Furthermore, the treatment enhanced the soil’s water stability. Microstructural analysis revealed that the formation of hydrated magnesium carbonates filled voids, cemented particles, and created a dense structural matrix. This densification of the internal structure underpinned the observed mechanical improvements. These findings validate EIMC as a feasible and effective eco-friendly technique for gravelly soil stabilization.

To address the need for enhanced geotechnical performance in gravelly soil stabilization, this study investigated the synergistic effects of guar gum as an additive in enzyme-induced calcium carbonate precipitation (EICP) treatment. Through systematic experimentation combining unconfined compressive strength (UCS) tests, carbonate content quantification, and triaxial analysis, the mechanical behavior of treated soils was evaluated under varying EICP solution concentrations (0–2 mol/L) and curing durations. Results demonstrated that a 1.5 mol/L EICP solution achieved peak strength and carbonate precipitation before subsequent decline, while a 1% guar gum dosage optimized mechanical properties by balancing initial strength enhancement and precipitation efficiency. Scanning electron microscopy revealed microstructural mechanisms wherein guar gum provided heterogeneous nucleation sites for calcite crystals, while its interaction with EICP enabled dual-phase pore filling and interparticle bonding. This synergistic effect created a three-dimensionally reinforced matrix, significantly improving both UCS and unconsolidated undrained shear strength compared to native and EICP-only specimens. The findings establish a theoretical framework for regulating calcite precipitation patterns and enhancing cementation mechanisms in gravelly soil improvement, offering practical guidelines for foundation engineering applications through the combined use of guar gum and EICP.

This study aims to analyze the impact of varying dosages of N-(n-butyl) thiophosphoric triamide (NBPT) on the physical and mechanical properties of microbial-induced calcite precipitation (MICP) grouting improved red clay. The research includes XRD and SEM experiments to examine the micro-structural characterization of the specimens and understand the mechanism of NBPT's action on MICP improved red clay. A comprehensive evaluation is conducted to assess the properties of red clay after the introduction of NBPT microbial improvement, the results show that The mechanical properties and peak strength of MICP improved red clay samples showed a tendency to increase and then decrease with the increase of NBPT doping, and the stress-strain curve showed a change from softening to hardening and then back to softening; the improvement effect was in the optimal state at the cut-off point when the doping amount of NBPT was 0.1%. The shrinkage deformation, initial water content, and shrinkage coefficient of the MICP improved red clay samples decreased gradually as the doping amount of NBPT increased. In the residual shrinkage deformation stage (δs2), the water content of the specimen needed to reach the ultimate linear shrinkage gradually increased with NBPT doping, causing it to enter the stable shrinkage deformation stage (δs3) earlier. The difference in CaCO₃ content between the upper and lower parts of the specimens gradually decreased with the increase of NBPT doping, and finally tends to be stabilized. The urease inhibitor NBPT can affect the crystal morphology and distribution of the product and intervene in the morphological transformation of vaterite to calcite.