Since the cyanide ion is used in a wide range of industries and is harmful to both human health and the environment, a number of research efforts are dedicated to creating fluorescence sensors for the detection of cyanide (CN⁻).

A new photochromic fluorescence chemosensor was devised and effectively synthesized using benzothiazole and imidazopyridine derivatives. A “turn-on” fluorescence sensor BIPP for Zn²⁺ detection was developed and has a quick response, excellent sensitivity, and remarkable selectivity over other metal ions. When Zn²⁺ was added to the BIPP solution, a new strong fluorescence emission peak at 542 nm formed with a considerable increase in intensity. The fluorescence color of the BIPP solution changed from blue to bright green. The binding ratio 8 : 2 was found between BIPP and Zn²⁺ by the results of Job's plot, HRMS and ¹H-NMR. The detection limit (LOD) of BIPP towards Zn²⁺ was determined to be 2.36 × 10⁻⁸, which is remarkably low. The ability to detect Zn²⁺ in real water samples demonstrates that BIPP may also be used in environmental systems. Additionally, BIPP can be used to measure Zn²⁺ levels in living cells.

A simple 1,8-naphthalimide based Schiff base probe NDSM has been designed and synthesized for the specific detection of Fe³⁺ based on a fluorimetric mode.

Hydrothermally assisted magnetic ZnO/Carbon nanocomposites were prepared using the selective biowaste of pomelo orange. Initially, the carbon aerogel (CA) was prepared hydrothermally followed by a freeze-drying method. Furthermore, the iron oxide nanoparticles were deposited onto the surface of carbon using the co-precipitation method and we obtained magnetic carbon nanocomposite, i.e., Fe₃O₄/C (MNC). Moreover, the ZnO photocatalysts were incorporated onto the surface of MNC composites using a hydrothermal process, and we obtained ZnO/MNC composites. The ZnO/MNC (55%), ZnO/MNC (65%) and ZnO/MNC (75%) composites were prepared by a similar experimental method in order to change the weight ratio of ZnO NPs. Using a similar synthetic procedure, the standard ZnO and Fe₃O₄ nanoparticles were prepared without the addition of CA. The experimental results were derived from several analytical techniques, such as: X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman and diffuse reflectance spectroscopy (DRS-UV). The synthesized carbon, ZnO, Fe₃O₄, ZnO/MNC (55%), ZnO/MNC (65%) and ZnO/MNC (75%) composites were examined through the photocatalytic degradation of methylene blue (MB) under visible-light irradiation (VLI). The obtained results revealed that the composites were more active than carbon, ZnO and Fe₃O₄. In particular, the ZnO/MNC (75%) composites showed more activity than the rest of the composites. Furthermore, the recycling abilities of the prepared ZnO/MNC (75%) composites were examined through the degradation of MB under identical conditions and the activity remained constant up to the fifth cycle. The synthetic procedure and practical applications proposed here can be used in chemical industries, biomedical fields and energy applications.

Acetic acid–promoted, one-pot synthesis of tetrahydropyridines has been developed under metal-catalyst-free conditions via a tandem reaction. High atom economy, good yield, simple procedure, no expensive column chromatography, shorter reaction time, and metal-free and mild reaction conditions are some of the important features of this protocol. The current methodology provides an alternative approach for not only highly substituted tetrahydropyridines (THPs) but also fully substituted tetrahydropyridines (FTHPs) in moderate to good yields. The plausible mechanism for the formation of THPs was greatly promoted by the H⁺ ion coming from acetic acid. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.]