Pablo Amezqueta

Mr. Pablo Amezqueta

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Research Focus & Metrics

Academic Career Length

2Years (2025-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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19 February 2025 in Ceramics
Verified
Journal Article
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JMJennifer Moriones
Jennifer Moriones
JOJavier Osés
Javier Osés
PAPablo Amezqueta
Pablo Amezqueta
JPJOSE PALACIO
JOSE PALACIO
JAJonathan Fernández de Ara
Jonathan Fernández de Ara
EAEluxka Almandoz
Eluxka Almandoz
Exposure to short-wavelength light, including UV-A and blue light, can degrade high-value products like rosé wine, which are usually packaged in colourless bottles. This study investigates the optimisation of sol–gel coatings enhanced with UV-absorbing additives (Tinuvin 479 and semaSORB 20109) to provide photoprotection for rosé wines. Coatings with varying additive concentrations (0.5%, 0.75%, 1%, and 1.5%) were applied to glass substrates via spin coating and cured with UV light. Then, optical and mechanical characterisation was performed. The 1.5% concentration semaSORB 20109 bilayer coating demonstrated improved photoprotective properties without compromising colour properties, leading to successful application on glass bottles by spray coating. Accelerated degradation tests confirmed that the optimised coating effectively protected against photodegradation, as indicated by the stability of polyphenol levels and colour parameters in rosé wines. The results suggest that these coatings could be a suitable option for commercial-scale applications, enhancing the light resistance of colourless-bottled products.

23 June 2025 in Materials
Verified
Journal Article
Open access
PDF file
GFGonzalo Garcia Fuentes
Gonzalo Garcia Fuentes
MBMarya Baloch
Marya Baloch
JPJOSE PALACIO
JOSE PALACIO
PAPablo Amezqueta
Pablo Amezqueta
RBRebeca Bueno
Rebeca Bueno
GAGermán Alcalá
Germán Alcalá
In this study, we investigated the frictional properties of TiB2 films produced by high-power impulse magnetron sputtering and compared them with those of TiN- and CrN-sputtered coatings also made using high-power pulsed discharges. The films were characterised by scanning electron microscopy, Electron Probe Micro-Analysis, nanoindentation and friction tests. Sliding friction analyses were performed against aluminium surfaces at different temperatures, ranging from room temperature to 300 °C. The TiB2 coatings exhibited hardness values of about 39 GPa, regardless of the bias potential used between −50 V and −100 V, a low modulus of around 300 GPa and a dense compact columnar microstructure with grain sizes between 51 and 68 nm in diameter. The friction behaviour on aluminium produced the transfer of this element to the films, at rates that depended on the test temperature. The TiN and CrN coatings exhibited low–medium adhesion to aluminium at room temperature and severe transfer during the friction tests at 150 °C. In the case of the TiB2 films, the adhesion of aluminium during friction tests was low for temperatures up to 175 °C. In fact, a clear transition of the mild-to-severe adhesion of aluminium on TiB2 was observed in the temperature range of 175 °C to 200 °C for the testing conditions evaluated in this study, which was concomitant with the evolution observed for the friction coefficients.