A new seedless wet chemistry synthesis of gold nanorods by using hydrogen peroxide as the weak reducing agent is reported. A reduced concentration of hexadecyltrimethylammonium bromide is used in our experiment, and the synthesized gold nanorods exhibit tunable longitudinal surface plasmon resonance peaks ranging from 725 to 945 nm. The influence on gold nanorods growth by adjusting the amounts of sodium hydroxide, silver nitrate, sodium borohydride, and hexadecyltrimethylammonium bromide were investigated by the visible-near infrared spectroscopy. Under the proper experimental parameters, the longitudinal surface plasmon resonance peaks can be tuned by varying the hydrogen peroxide amounts. Furthermore, it can be seen that the redshift of the longitudinal absorption peak of the prepared gold nanorods with increasing hydrogen peroxide amount is consistent with the increase tendency of the length-to-width aspect ratio obtained from the transmission electron microscopy images. The method provides a facile pathway to prepare gold nanorods with tunable longitudinal surface plasmon resonance peaks, which have potential applications in biomedicine and nanophotonics.

In deep underground engineering applications, such as coal mining, coal–rock masses are frequently subjected to repeated loading and unloading conditions. Understanding the evolution mechanisms of their internal three-dimensional fracture fields has become a critical scientific challenge. This study utilized X-ray Microscopy (XRM) to observe changes in internal fractures of coal samples after each loading–unloading cycle, reconstructing the internal fractures and mineral particles. Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS) were employed to analyze the surface morphology and mineral composition of coal sample cross-sections. The experimental results revealed that: (1) With an increasing number of loading–unloading cycles, the samples’ volumes initially decreased and then expanded, with the expansion accompanied by rapid propagation of CT-scale fractures; (2) During the linear elastic phase, micro-fractures developed progressively but remained small, while sustained stress caused these fractures to interconnect, eventually leading to macroscopic failure; (3) Hard mineral particles within the coal samples, such as iron ore, acted as barriers to crack propagation. These findings indicate that the evolution characteristics of the internal fracture fields in coal–rock masses are influenced by stress state, pre-existing fractures, and the distribution of mineral particles.