Coal mining disrupts soil structure and causes water loss, thereby affecting the ecological environment of mining areas. Rapid, accurate, and non-destructive detection of surface soil moisture is crucial for advancing ecological restoration in these regions. This study focuses on the mined and unmined areas of the Yushuquan coal mine, located on the southern slope of the Tianshan Mountains in Xinjiang, China. The soil volumetric water content (SVWC) was measured using time-domain reflectometry (TDR), while the shallow subsurface soil was investigated using ground-penetrating radar (GPR). Various features were extracted from GPR signals in both the time- and frequency-domains, and their relationships with SVWC were analyzed. Multiple features were selected and optimized to determine the optimal feature combination for building a multi-feature backpropagation neural network model for soil volumetric water content prediction (Muti-BP-SVWC). The performance of this model was compared with two single-feature-based methods for SVWC prediction: the average envelope amplitude (AEA) method and the frequency shift method. The application results of the Muti-BP-SVWC model in different regions demonstrated significant improvements in accuracy and stability compared to the AEA method and the frequency shift method. In the mined area validation set, the model achieved an determination coefficient (R²) of 0.77 and the root mean square error (RMSE) of 0.0091 cm³/cm³, while in the unmined area validation set, the R² of 0.84 and an RMSE of 0.0059 cm³/cm³. These results indicate that incorporating multiple features into the BP neural network can better capture the complex relationship between GPR signals and SVWC. This approach effectively inverts the shallow subsurface soil moisture in mining areas and provides valuable guidance for ecological restoration in these regions.