Soil aggregate stability is an important aspect of soil function and health. Fertilization could potentially alter soil properties and thereby affect aggregate stability. To determine which fertilizer is useful for improving soil fertility and stabilizing soil aggregates and thereby reducing soil erodibility, we examined three types of fertilizer, and measured how soil organic carbon, carbohydrates, and related soil properties influenced aggregate stability in eroded Ultisols. Treatments included control (CK), mineral fertilizer nitrogen (N), phosphorus (P), potassium (K) (NPK), fertilizer NPK plus straw (NPKS), and farmyard manure (FYM). Aggregate stability was tested according to Le Bissonnais method, involving three disruptive tests: fast wetting (FW), slow wetting (SW), and mechanical breakdown (WS). Total organic carbon, particulate organic carbon, mineral-associated carbon, and cold-water-soluble carbohydrate, hot-water-soluble carbohydrate, and dilute acid hydrolysable carbohydrate were measured, as well as soil intrinsic properties (including pH, bulk density, iron and aluminum oxides). The 12-year fertilization had a larger effect on aggregate stability and related soil properties in a 0–15 cm soil layer, whereas no effect was evident at a soil depth of 15–40 cm. MWD (mean weight diameter) under the three tests decreased with increasing soil depth. Fertilization, especially farmyard manure evidently improved MWD_FW and MWD_WS at a depth of 0–15 cm. Slaking was the main mechanism of aggregate breakdown in Ultisols studied, followed by mechanical breakdown. Correlation analysis showed that MWD_FW and MWD_WS at a depth of 0–15 cm increased with the increase of particulate organic carbon, total organic carbon, hot-water-soluble carbohydrate and pH. Furthermore, their interaction with amorphous iron oxides enhanced aggregate stability against slaking or, with amorphous aluminum oxides, modified aggregate stability against mechanical breakdown. Consequently, particulate organic carbon was the dominant cementing agent for aggregation in Ultisols studied, and its combination with pH, amorphous aluminum oxides, amorphous iron oxides, and free aluminum oxides play a synergetic role in stabilizing soil aggregate. Accordingly, farmyard manure or fertilizer NPK plus straw improved soil fertility and the ability to resist slaking.

In the mountainous area of China, the rock fragments in top soils are often removed by farmers because of their side effects on tillage. To understand hydrological processes and to assess the risk of soil erosion in purple soil areas with sloping farmlands, this study investigated the effects of rock fragment cover on surface runoff, infiltration, subsurface runoff, and erosion under field conditions using a portable rainfall simulator. Experimental twin plots (two subplots, 1 m wide by 2 m long, 32% slope) with different rock fragment covers ranging from 0 to 42% were exposed to four rainfall intensities: $45.5\pm 1.9\mathrm{mm}/\mathrm{h}$ (I1), $60.3\pm 3.6\mathrm{mm}/\mathrm{h}$ (I2), $92.0\pm 4.1\mathrm{mm}/\mathrm{h}$ (I3), and $123.9\pm 9.4\mathrm{mm}/\mathrm{h}$ (I4). Surface runoff, subsurface runoff, soil moisture, and sediment were measured. The results show that the hydrological response was influenced by the rock fragment cover and rainfall intensity. The rate of surface runoff in bare soils was affected by the rainfall intensity and increased with increasing rainfall intensity. The values of the surface runoff rates in bare soils were lower than $70\mathrm{mm}/\mathrm{h}$ under the I1, I2, and I3 rainfall intensities. As the rock fragment cover increased, the surface runoff rate decreased while the infiltration rate, the subsurface runoff rate and the deep percolation coefficient increased. On the other hand, when the surface runoff rates in the bare soils were higher than $70\mathrm{mm}/\mathrm{h}$ (in rainfall of I4), there were no significant differences in these hydrological variables among soils with different rock fragment covers. The differences in hydrological variables among soils with varying rock fragment covers decreased with increasing rainfall intensity. The rock fragment cover determined the erosive response. As the rock fragment cover increased, the sediment concentration decreased. The presence of surface rock fragments significantly reduces soil erosion, and the relationship between the soil erosion rate and rock fragment cover can be expressed by an exponential function with a high degree of reliability for different rainfall intensities. However, the effectiveness of the rock fragment cover in reducing soil erosion decreased with increasing rainfall intensity.