In recent years vulnerability maps have been used as a tool to highlight the areas with the greatest potential for groundwater pollution based on the hydrogeological conditions and their respective human impacts. Several regions of Greece depend completely or partially on drinking water from karst aquifers; thus, the production of vulnerability maps for such karstic areas is considered essential. In the present study, an assessment of aquifer intrinsic vulnerability has been conducted applying the COP method in the Ziria karst system. The latter is located at the Northeast part of Peloponnese in South Greece and is used as a public resource for drinking water. This method, which has been developed for carbonate (karst) aquifers, uses the properties of the overlying layers above the water table (O factor), the concentration of flow (C factor) and the precipitation regime (P factor) over the aquifer. The COP method considers karstic landforms as factors that decrease the natural protection provided by the overlying layers of a karst aquifer. With the use of GIS tools, vulnerability maps were produced highlighting the different degrees of intrinsic vulnerability in the karst system of Ziria.

On the outskirts of the Pinios dam reservoir (Ilia Regional Unit, Greece), a water treatment plant serves the water supply needs of the surrounding municipalities, in which high concentrations of Fe and Mn, before treatment, have been observed. The main purpose of this research was to investigate the mechanism of increased iron (Fe) and manganese (Mn) levels in the reservoir of the Pinios dam, which impacts its water treatment plant operation. A wide range of hydrochemical and sedimentological analyses were conducted over a hydrological year, focusing on the spatial and temporal distribution of Fe and Mn in both water and sediment samples across the established research monitoring stations. Sediment samples from the reservoir’s bottom revealed predominantly fine-grained material, rich in total organic carbon, with elevated Mn and Fe oxide levels. Significant seasonal variations in Fe and Mn levels were also discovered, with higher Mn levels observed in the anoxic bottom waters of the reservoir during the dry season, attributed to the reduced conditions favoring Mn oxide dissolution over Fe. Conversely, during the wet season, a homogenization of metal concentrations throughout the water column was observed due to increased oxygenation and freshwater inflow. These outcomes were confirmed by the hydrochemical analysis, indicating that the redox conditions, pH, and temperature, as well as the presence of organic matter, significantly influence the mobility and bioavailability of these metals in the reservoir. The findings of this study clarify that the high concentration of Fe and Mn can be linked to the mineral composition of the upstream Neogene and flysch formations in the study area. As these formations are affected by geological weathering, they tend to enrich the streams, through soil erosion and runoff processes, with metals like Fe and Mn, which are eventually transported into the dam reservoir. This study highlights the critical influence of lithological, sedimentological, and hydrological factors on the redox conditions and seasonal stratification that govern the behavior of Fe and Mn concentrations and mobility in dam reservoirs. These findings are critical for informing water resource management practices and dam infrastructure operators and developing effective environmental conservation strategies in similar cases.

Groundwater sustains ecosystems, agriculture, and human consumption; therefore, its interaction with hydrocarbons is an important area of research under the umbrella of environmental science and resource exploration. Naturally occurring or anthropogenically introduced hydrocarbons can significantly impact groundwater through complex geochemical processes such as dissolution, adsorption, biodegradation, and redox reactions and can also affect groundwater chemistry in terms of pH, redox potential, dissolved organic carbon, and trace element concentrations. Accurate determination and identification of hydrocarbon contaminants requires advanced analytical methods like gas chromatography, GC–MS, and fluorescence spectroscopy, complemented with isotopic analysis and microbial tracers, which provide insights into sources of contamination and biodegradation pathways. The presence of hydrocarbons in groundwater is a matter of environmental concern but can also valuable data for petroleum exploration, tracing subsurface reservoirs and seepage pathways. This paper refers to the basic need for geochemical investigations combined with advanced detection techniques for successful regulation of thermal–mineral groundwater quality. This contributes towards successful sustainable hydrocarbon resource exploration and water resource conservation, with emphasis on the relationship between groundwater quality and hydrocarbon exploration. The study points out the significance of continuous observation of thermal mineral waters to identify their connection with the specific hydrocarbons of each study area.

The recharge of karst aquifers is significant for the effective management of groundwater resources, and its estimation should be tailored to accommodate their specific hydrogeological characteristics. This study provides a two-step methodological approach for the determination of karst aquifer recharge. Initially, mean annual recharge rates were estimated in the karst system of Ziria (Southern Greece) utilizing the APLIS and modified APLIS methods in order to decipher which was the most suitable version for recharge assessments. The results indicated similar mean recharge rate values at 42.7% and 41.4%, respectively, but significant differences in the spatial distribution. The modified methodology emerged as a more accurate and realistic approach, mainly due to the incorporation of permeability assessments. The final phase of the methodological approach involved the application of modified APLIS in two additional karst hydrosystems, Planitero and Xiromero, while a quantitative cross-comparison of the recharge rates was obtained for a deeper understanding of the factors controlling the groundwater recharge process. In Ziria, recharge rates exhibit a relatively uniform distribution throughout the area, with a median value of 46.7%. Conversely, in Planitero, High recharge rates (60–80%) occupy 56.8% of the surface, while in Xiromero, Moderate recharge rates (40–60%) dominate, representing 53.4% of the land coverage. These variations underscore the spatial heterogeneity of recharge within the karst systems, highlighting the importance of considering local geological and hydrological conditions in its assessments. The methodological approach of this study is flexible and can be adapted to different karst sites for the determination of recharge regimes, contributing to the alleviation of the groundwater depletion issue.

This study aims to investigate the intricate relationship between geological structures, water chemistry, and isotopic composition in order to gain a deeper understanding of the origins and recharge mechanisms of thermal–mineral waters in the Kyllini region. The research integrates tectonic analysis, hydrochemical data, and stable isotope measurements to delineate recharge zones and trace the origin of these unique water sources. The methods used for delineation are the geological and tectonic study of the area, as well as hydrochemical and isotopic data analysis. The findings highlight that tectonic activity creates preferential flow paths and consequently influences the hydrogeological framework, facilitating deep circulation and the upwelling of thermal waters. Monthly analyses of groundwater samples from the Kyllini thermal spring were conducted over one hydrological year (2019–2020) and compared with data from the area collected in 2009. The hydrochemical profiles of major and minor ions reveal distinct signatures corresponding to various water–rock interactions, while stable isotope analysis provides insights into the climatic conditions and altitudes of recharge areas. Hydrochemical analyses reveal the composition of thermal–mineral waters, aiding in the identification of potential sources and their evolution. The conceptualization of Kyllini contributes to the deeper understanding of the intricate interplay between tectonics, hydrochemistry, and stable isotopes. During a hydrological year, the water type of Kyllini’s spring groundwater remains the same (Na-Cl-HCO₃), presenting only slight alterations.