Colloidal photonic crystal (PC)-based anti-counterfeiting materials have been widely studied due to their inimitable structural colors and tunable photonic band gaps (PBGs) as well as their convenient identification methods. In this review, we summarize recent developments of colloidal PCs in the field of anti-counterfeiting from aspects of security strategies, design, and fabrication principles, and identification means. Firstly, an overview of the strategies for constructing PC anti-counterfeiting materials composed of variable color PC patterns, invisible PC prints, and several other PC anti-counterfeiting materials is presented. Then, the synthesis methods, working principles, security level, and specific identification means of these three types of PC materials are discussed in detail. Finally, the summary of strengths and challenges, as well as development prospects in the attractive research field, are presented.

Nowadays, many kinds of colloidal photonic crystal (PC) sensors with inverse opal (IO) structures have been developed. However, there are few systematic studies on the factors influencing their recognition capability and responsiveness capability. In this paper, the relationships between recognition capability of IO structured PC sensors and all the parameters in Bragg–Snell’s law have been explored. In addition, research on the recognition ability of PC sensors typically focuses only on the refractive index difference between the identified substances. Herein, we define two concepts, namely the absolute refractive index difference and the relative refractive index difference, and prove that the recognition ability not only relies on the absolute refractive index between the identified substances, but also on the relative refractive index. Bragg–Snell’s law analysis confirms that the responsiveness capability is directly proportional to the void size of the IO structure, which is also confirmed by the finite difference time domain (FDTD) method. It is believed that these systematic studies have important guiding significance for creating advanced IO structured PC sensors.