Alkali-activated cementitious materials, as an environmentally friendly cementitious material, can effectively reduce carbon emissions and improve the utilisation of solid wastes. However, traditional strong alkali activators have limitations such as high carbon emissions and poor safety. In order to overcome the defects of traditional strong alkaline activators and realise the high value-added use of calcium carbide residue (CCR), this paper adopts CCR as an alkaline activator to activate granulated blast furnace slag (GBFS)-steel slag (SS) cementitious systems for the preparation of alkaline-activated cementitious materials. The effects of CCR content and SS content on the compressive strength and working performance of CCR-GBFS-SS cementitious systems are analysed, along with the hydration process of CCR-GBFS-SS cementitious systems and the mechanism of action through the hydration products, their chemical structure and their microscopic morphology. The research results show that CCR-GBFS-SS cementitious systems have a 28-day compressive strength of 41.5 MPa and they can be controlled by the setting time; however, the flow performance is poor. The SS content can be increased to improve the flow performance; however, this will reduce the compressive strength. In CCR-GBFS-SS cementitious systems, CCR is the main driving force of hydration reactions, GBFS mainly provides active silica and aluminium and the amorphous C-(A)-S-H gel and ettringite formed by the synergistic action of multiple solid wastes are the main sources of compressive strength. With the extension of the curing time, the amount of hydration products in the cementitious systems gradually increases and the matrix of the cementitious systems gradually becomes denser. This study will provide a reference for the consumption of low-value solid waste such as CCR and the preparation of low-carbon cementitious materials from multi-component solid wastes.

The preparation of iron ore tailings (IOTs) into supplementary cementitious materials (SCMs) is an effective approach to achieve value-added utilization of industrial solid waste. This study systematically investigates the hydration pattern and strength development of Portland cement systems with the incorporation of IOTs, steel slag (SS), granulated blast-furnace slag (GBFS), and fly ash (FA) under the action of different chemical additives. The hydration products, and microstructure and pore structure of the SCMs are analyzed using X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and mercury intrusion porosimetry. The findings of this study demonstrate that chemical activation plays a significant role in the strength development of SCMs. Among the five chemical activators tested, Triethanolamine (TEA) had the greatest influence on mechanical properties. The maximum compressive strength of the SCMs at 28 days was 42.9 MPa at a dosage of 1%. Specifically, the addition of TEA promotes volcanic ash reactions, and the high fineness of SCM provides nucleation sites for hydration products. Interactions between the volcanic ash reaction and the complexation reaction of TEA have a positive effect on compressive strength development. This research expands the potential for IOTs SCMs through chemical activation methods for value-added applications.

The ecological impacts of mining and the instability of slopes are the key factors restricting the safe, efficient, and low-carbon production of open-pit mines. This study focused on the ultimate pit limit (UPL) optimization under the concept of sustainability by integrating consideration of the economic benefit, ecological impact, and slope geometry. The integrated UPL optimization model based on the floating cone method was proposed by establishing a quantitative model for ecological impacts arising from open-pit coal mining in arid or semi-arid weak ecological land and a cost calculation model of slope reinforcement based on the Monte Carlo method. The case study revealed that steepening the slope angle of given regions resulted in random variations in the quantity of ore rock and the limit morphology. There was an average economic profit rise of USD 9.54M with every 1° increase in slope angle, but the probability of slope instability and the reinforcement cost grows exponentially. In the arid or semi-arid weak ecological land, the ecological costs exceeded 20% of the mines’ average pure economic gains. The proposed optimization method contributes to obtaining an integrated optimal UPL, improving the benefits and the ore recovery rate.

This paper presents a phase planning method specially designed for coal deposits with nearly horizontal, bedded coal seams. The geology of this type of deposit is modeled into a column model, instead of a block model, to avoid coal-rock mixing in blocks. A nested pit generation algorithm is developed for producing a series of nested, least-strip ratio pits with a column model as its input. The algorithm completely overcomes the troublesome gap problem. Taking the least-strip ratio pits as possible phase states, a dynamic programming formulation is proposed to simultaneously optimize the number of phases, the phase-pits, and the ultimate pit, with an objective of maximizing the net present value. The merits and capability of the proposed method are demonstrated through a case study on a large coal deposit.