A complete classification of shock waves in a van der Waals fluid is undertaken. This is in order to gain a theoretical understanding of those shock-related phenomena as observed in real fluids which cannot be accounted for by the ideal gas model. These relate to admissibility of rarefaction shock waves, shock-splitting phenomena, and shock-induced phase transitions. The crucial role played by the nature of the gaseous state before the shock (the unperturbed state), and how it affects the features of the shock wave are elucidated. A full description is given of the characteristics of shock waves propagating in a van der Waals fluid. The strength of these shock waves may range from weak to strong. The study is carried out by means of the theory of hyperbolic systems supported by numerical calculations.

The structure of a shock wave in a rarefied polyatomic gas is studied on the basis of the theory of extended thermodynamics. Three types of the shock wave structure observed in experiments, that is, the nearly symmetric shock wave structure (type A, small Mach number), the asymmetric structure (type B, moderate Mach number), and the structure composed of thin and thick layers (type C, large Mach number), are explained by the theory in a unified way. The theoretical prediction of the profile of the mass density agrees well with the experimental data. The well-known Bethe-Teller theory of the shock wave structure in a polyatomic gas is reexamined in the light of the present theory.

We study the shock wave structure in a rarefied polyatomic gas based on a simplified model of extended thermodynamics in which the dissipation is due only to the dynamic pressure. In this case the differential system is very simple because it is a variant of Euler system with a new scalar equation for the dynamic pressure [T. Arima, S. Taniguchi, T. Ruggeri, and M. Sugiyama, Phys. Lett. A 376, 2799–2803 (2012)]. It is shown that this theory is able to describe the three types of the shock wave structure observed in experiments: the nearly symmetric shock wave structure (Type A, small Mach number), the asymmetric structure (Type B, moderate Mach number), and the structure composed of thin and thick layers (Type C, large Mach number).