We report strong variations in the Raman spectra for different single-layer graphene samples obtained by micromechanical cleavage. This reveals the presence of excess charges, even in the absence of intentional doping. Doping concentrations up to are estimated from the peak shift and width and the variation of both position and relative intensity of the second order 2D peak. Asymmetric peaks indicate charge inhomogeneity on a scale of less than .
We report phonon renormalization in bilayer graphene as a function of doping. The Raman peak stiffens and sharpens for both electron and hole doping as a result of the nonadiabatic Kohn anomaly at the point. The bilayer has two conduction and valence subbands, with splitting dependent on the interlayer coupling. This gives a change of slope in the variation of peak position with doping which allows a direct measurement of the interlayer coupling strength.