A serials of biomimetic photocatalyst zinc(II) meso-tetra(4-carboxyphenyl)porphyrinato (ZnTCP)-sensitized 3D hierarchical TiO2 hollow nanoboxes (TiO2-HNBs) assembled by six ordered nanosheets with dominant {001} facets exposure (ZnTCP@TiO2-HNBs) have been successfully synthesized by a facile one-pot solvothermal method via a topological transformation process with TiOF2 as template. Infrared spectra (IR), UV-vis spectroscopy, and X-ray photoelectron spectroscopy (XPS) confirmed that ZnTCP played a decisive role in constructing 3D hollow nanoboxes through the formation of ester bond combined to TiO2-HNBs, which also provided a transferring photo excited electrons bridge to sensitize TiO2-HNBs for enhancing visible-light response. Due to the superior sensitization and biomimetic activity of ZnTCP, the photodegradation rate of rhodamine B (RhB) of as-prepared ZnTCP@TiO2-HNBs with ZnTCP/TiOF2 mass ratio of 2% (T-2p) improves 3.6 times compared to that of TiO2-HNBs with a degradation yield of 99% for 2 h under simulated sunlight irradiation (> 420 nm). The enhanced photodegradation ability was attributed to synergistic visible photocatalytic mechanism of biomimetic catalyst, which can not only produce hydroxyl radical (•OH) and superoxide radical (•O2−) coming from the excitation process of ZnTCP sensitized TiO2-HNBs, but also generate singlet oxygen (1O2) that was only provided by biomimetic enzyme porphyrins. Furthermore, the photocatalyst showed good recycling stability and dispersibility after five rounds, ascribed to ZnTCP strong chemical bonding to the support TiO2-HNBs. By means of electrochemical cyclic voltammetry analysis, the effect of central zinc ions and parent porphyrin rings on the redox property of biomimetic catalyst was studied.

A new composite by coupling chalcopyrite (CuFeS₂) with silver phosphate (Ag₃PO₄) (CuFeS₂/Ag₃PO₄) was proposed by using a cyclic microwave heating method. The prepared composites were characterized by scanning and transmission electron microscopy and X-ray diffraction, Fourier-transform infrared, UV–Vis diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. Under optimum conditions and 2.5 W irradiation (wavelength length > 420 nm, power density = 0.38 Wcm⁻²), 96% of rhodamine B (RhB) was degraded by CuFeS₂/Ag₃PO₄ within a 1 min photo-Fenton reaction, better than the performance of Ag₃PO₄ (25% degradation within 10 min), CuFeS₂ (87.7% degradation within 1 min), and mechanically mixed CuFeS₂/Ag₃PO₄ catalyst. RhB degradation mainly depended on the amount of hydroxyl radicals generated from the Fenton reaction. The degradation mechanism of CuFeS₂/Ag₃PO₄ from the photo-Fenton reaction was deduced using a free radical trapping experiment, the chemical reaction of coumarin, and photocurrent and luminescence response. The incorporation of CuFeS₂ in Ag₃PO₄ enhanced the charge separation of Ag₃PO₄ and reduced Ag₃PO₄ photocorrosion as the photogenerated electrons on Ag₃PO₄ were transferred to regenerate Cu²⁺/Fe³⁺ ions produced from the Fenton reaction to Cu⁺/Fe²⁺ ions, thus simultaneously maintaining the CuFeS₂ intact. This demonstrates the synergistic effect on material stability. However, hydroxyl radicals were produced by both the photogenerated holes of Ag₃PO₄ and the Fenton reaction of CuFeS₂ as another synergistic effect in catalysis. Notably, the degradation performance and the reusability of CuFeS₂/Ag₃PO₄ were promoted. The practical applications of this new material were demonstrated from the effective performance of CuFeS₂/Ag₃PO₄ composites in degrading various dyestuffs (90–98.9% degradation within 10 min) and dyes in environmental water samples (tap water, river water, pond water, seawater, treated wastewater) through enhanced the Fenton reaction under sunlight irradiation.

In this study, Chalcopyrite (CuFeS₂) was prepared by a hydrothermal and co-precipitation method, being represented as H-CuFeS₂ and C-CuFeS₂, respectively. The prepared CuFeS₂ samples were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), energy dispersive X-ray spectroscopy mapping (EDS-mapping), powder X-ray diffractometer (XRD), X-ray photoelectron spectrometry (XPS), and Raman microscope. Rhodamine B (RhB, 20 ppm) was used as the target pollutant to evaluate the degradation performance by the prepared CuFeS₂ samples. The H-CuFeS₂ samples (20 mg) in the presence of Na₂S₂O₈ (4 mM) exhibited excellent degradation efficiency (98.8% within 10 min). Through free radical trapping experiment, the major active species were •SO₄⁻ radicals and •OH radicals involved the RhB degradation. Furthermore, •SO₄⁻ radicals produced from the prepared samples were evaluated by iodometric titration. In addition, one possible degradation mechanism was proposed. Finally, the prepared H-CuFeS₂ samples were used to degrade different dyestuff (rhodamine 6G, methylene blue, and methyl orange) and organic pollutant (bisphenol A) in the different environmental water samples (pond water and seawater) with 10.1% mineral efficiency improvement comparing to traditional Fenton reaction.

This study demonstrated facile synthesis of silver phosphate (Ag₃PO₄) photocatalysts for the degradation of organic contaminants. Ag₃PO₄ microparticles from different concentrations of precursor, AgNO₃, were produced and characterized by scanning electron microscopy, powder X-ray diffraction, and UV–visible diffuse reflectance spectroscopy. Degradation rates of methylene blue (MB) and phenol were measured in the presence of microparticles under low-power white-light light-emitting-diode (LED) irradiation and the reaction rate followed pseudo-first-order kinetics. The prepared Ag₃PO₄ microparticles displayed considerably high photocatalytic activity (>99.8% degradation within 10 min). This can be attributed to the microparticles’ large surface area, the low recombination rate of electron–hole pairs and the higher charge separation efficiency. The practicality of the Ag₃PO₄ microparticles was validated by the degradation of MB, methyl red, acid blue 1 and rhodamine B under sunlight in environmental water samples, demonstrating the benefit of the high photocatalytic activity from Ag₃PO₄ microparticles.

Dendritic forest-like Ag nanostructures were deposited on a silicon wafer through fluoride-assisted galvanic replacement reaction (FAGRR) in aqueous AgNO₃ and buffered oxide etchant. The prepared nanostructures were characterized using scanning electron microscopy, energy-dispersive X-ray spectroscopy, inductively coupled plasma–optical emission spectroscopy, a surface profiler (alpha step), and X-ray diffraction. Additionally, the dendritic forest-like Ag nanostructures were characterized using surface-enhanced Raman scattering (SERS) when a 4-mercaptobenzoic acid (4-MBA) monolayer was adsorbed on the Ag surface. The Ag nanostructures exhibited intense SERS signal from 4-MBA because of their rough surface, and this intense signal led to an intense local electromagnetic field upon electromagnetic excitation. The enhancement factor for 4-MBA molecules adsorbed on the Ag nanostructures was calculated to be 9.18 × 10⁸. Furthermore, common Raman reporters such as rhodamine 6G, 4-aminothiolphenol, 5,5′-dithiobis-2-nitrobenzoic acid, and carboxyfluorescein (FAM) were characterized on these dendritic forest-like Ag nanostructures, leading to the development of an ultrasensitive SERS-based DNA sensor with a limit of detection of 33.5 nM of 15-mer oligonucleotide.