In this study, we report a single-step continuous production of straight-chain liquid hydrocarbons from oleic acid and other fatty acid derivatives of interest including castor oil, frying oil, and palm oil using Mo, MgO, and Ni on Al₂O₃ as catalysts in subcritical water. Straight-chain hydrocarbons were obtained via decarboxylation and hydrogenation reactions with no added hydrogen. Mo/Al₂O₃ catalyst was found to exhibit a higher degree of decarboxylation (92%) and liquid yield (71%) compared to the other two examined catalysts (MgO/Al₂O₃, Ni/Al₂O₃) at the maximized conditions of 375 °C, 4 h of space time, and a volume ratio of 5:1 of water to oleic acid. The obtained liquid product has a similar density (0.85 kg/m³ at 15.6 °C) and high heating value (44.7 MJ/kg) as commercial fuels including kerosene (0.78–0.82 kg/m³ and 46.2 MJ/kg), jet fuel (0.78–0.84 kg/m³ and 43.5 MJ/kg), and diesel fuel (0.80–0.96 kg/m³ and 44.8 MJ/kg). The reaction conditions including temperature, volume ratio of water-to-feed, and space time were maximized for the Mo/Al₂O₃ catalyst. Characterization of the spent catalysts showed that a significant amount of amorphous carbon deposited on the catalyst could be removed by simple carbon burning in air with the catalyst recycled and reused.

Synthesis of activated carbon from waste biomass is of current interest towards sustainability. The properties of biomass-derived activated carbon largely depend on the carbonization process. This study reports the preparation of mesoporous activated carbon with extremely high surface area from hemp bast fiber using hydrothermal processing. Hot water processing (390–500 °C) followed by activation using KOH and NaOH was investigated at different mass ratios. The described approach was found to enhance the mesoporosity (centered at 3.0 to 4.5 nm) of the hemp-derived activated carbon (HAC) from activation [confirmed by BJH (Barrett-Joyner-Halenda) pore size distribution and TEM (transmission electron microscopy) imaging]. BET (Brunauer-Emmett-Teller) results showed that the product has an extremely high surface area (2425 m²/g) while the surface functional groups (–OH, –COOH, C=C/C–C) were confirmed by FTIR (Fourier transform infrared spectroscopy) and further quantified by XPS (X-ray photoelectron spectroscopy). Increasing KOH concentration was found to enhance the surface area with a maximum biochar-to-KOH (g/g) ratio of 1:3. The crystallite domain size of HAC was determined using Raman spectroscopy of different wavelengths. The procedure described in this study is an environmentally friendly scalable route for the mass production of activated carbon using hemp fiber.