In this study, fumed silica (FS) was used as a support material and infused with the hydrated salt sodium hydrogen phosphate dodecahydrate (DHPD) to create shape-stabilized constant phase change materials (CPCMs). These CPCMs were integrated into a polyurethane matrix as a functional filler, resulting in low-exothermic polyurethane composite foams (CPCM-RPUFs) that demonstrate thermoregulation and flame-retardant properties. Recent findings show that CPCM-RPUF excels in thermal stability compared to pure polyurethane, with a melt phase transition enthalpy of 115.8 J/g. The use of fumed silica allows for the encapsulation of hydrated salts up to 87%, ensuring the structural integrity of the vesicles. As FS content in CPCMs increased, the internal temperature of the composite foam significantly decreased, showing excellent thermal regulation. Thermogravimetric analysis showed that the synergistic effect of DHPD and FS improved the thermal stability and flame retardancy of the composites. By monitoring the internal and surface temperature changes in the foam, it was verified that CPCMs can effectively alleviate heat accumulation during the curing process and reduce the core temperature (56.9 °C) and surface warming rate, thus realizing the thermal buffering effect. With the increase in FS content in CPCMs, the compressive strength of CPCM-RPUF can be maintained or even enhanced. This study provides a theoretical basis and technical support for the development of polyurethane composite foams with integrated thermal regulation and flame-retardant properties, which can have broad application prospects in the fields of building energy conservation, energy storage equipment, and thermal mine insulation.

This study establishes a numerical simulation model based on heat and mass transfer theory to reflect the variations in temperature and humidity conditions within a tunnel. It analyzes the impact of high-temperature fissure water, humid porous media, and drainage methods on the temperature and humidity distribution in a tunnel. The results indicate the following: (1) When the area of the humid porous media increases from 150 m² to 300 m², the relative humidity (RH) of the air in the tunnel rises from 52.7% to 55.8%, but the impact on air temperature (T_a) is minimal. (2) The heating and humidification effects of hot water in a drainage ditch on the airflow cannot be overlooked. Meanwhile, the hot water transfers heat to the surrounding rock, with heat transfer predominantly driven by the surrounding rock convection. Compared to a drainage pipe, the heat transfer amount increases by 44.9%, and RH rises by 9.3%. (3) For every increase of 5 °C in water temperature (water volume of 90 m³/h), the ventilation outlet T_a linearly increases by 0.15 °C, and the rate of increase in RH accelerates with rising water temperature. (4) Covering a drainage ditch with a cover plate can reduce RH by 12.3%, while spraying a 10 cm insulation layer on the tunnel walls can significantly lower T_a by 0.66 °C. These findings provide a potential solution for the application of insulation materials in reducing the thermal hazards of deep high temperatures.