In this work, we report the formation of multiple mode-locking states in an Erbium/Ytterbium co-doped fiber laser, such as domain-wall (DW) dark pulses, high-order dark harmonic pulses, dissipative soliton resonance (DSR) pulses, and dual-wavelength h-shaped pulses. By increasing the pump power and adjusting the quarter-wave retarder (QWR) plates, we experimentally achieve 310th-order harmonic dark pulses. DSR pulses emerge at a pump power of 1.01 W and remain stable up to 9.07 W, reaching a maximum pulse width of 676 ns and a pulse energy of 1.608 µJ, while Dual-wavelength h-shaped pulses have a threshold of 1.42 W and maintain stability up to 9.07 W. Using a monochromator, we confirm that these h-shaped pulses result from the superposition of a soliton-like pulse and a DSR-like pulse, emitting at different wavelengths but locked in time. The fundamental repetition rate for dark pulsing, DSR, and h-shaped pulses is 321.34 kHz. This study provides new insights into complex pulse dynamics in fiber lasers and demonstrates the versatile emission regimes achievable through precise pump and polarization control.

A passively Q-switched Thulium-doped fiber laser based on glycerin as the saturable absorber is experimentally demonstrated for the first time. The saturable absorber consists of two FC/PC connectors aligned within a mechanical fiber-fiber coupler, with the intervening gap filled with glycerin. Such a saturable absorber is integrated into a compact ring cavity, enabling passive Q-switched laser operation. Starting at a minimum pump power of 1.7 W, Q-switched pulses with a central wavelength of 1946 nm are obtained. At the maximum pump power of 2.4 W, the laser generates pulses with a duration of approximately 2 µs, a repetition rate of 26.7 kHz, and a pulse energy of 1.08 µJ. To the best of our knowledge, this is the first demonstration of passively Q-switched laser operation utilizing a glycerin-based saturable absorber for generating pulsed emission at the 2-µm wavelength region. This breakthrough represents a significant advancement in fiber laser technology, introducing a novel and efficient approach to pulse generation.